Research output: Contribution to journal › Article › peer-review
Influence of fluorosubstitution on the structure of zinc phthalocyanine thin films. / Klyamer, Darya D.; Sukhikh, Aleksandr S.; Gromilov, Sergey A. et al.
In: Macroheterocycles, Vol. 11, No. 3, 01.01.2018, p. 304-311.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Influence of fluorosubstitution on the structure of zinc phthalocyanine thin films
AU - Klyamer, Darya D.
AU - Sukhikh, Aleksandr S.
AU - Gromilov, Sergey A.
AU - Kruchinin, Vladimir N.
AU - Spesivtsev, Evgeniy V.
AU - Hassan, Aseel K.
AU - Basova, Tamara V.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - In this work, thin films of tetrafluorosubstituted zinc phthalocyanine (ZnPcF4) were deposited by organic molecular beam deposition and studied to reveal the effects of F-substituents on the ZnPcF4 single crystals and thin films structure. A combination of spectral ellipsometry, atomic force microscopy and diffraction techniques has been used to elucidate the structural features and molecular orientation of thin films of ZnPcF4. Structural features of the films grown by co-evaporation of ZnPc and ZnPcF4 (1:1) were also considered. Both ZnPcF4 and ZnPc/ZnPcF4 films have a preferred orientation along (001) plane with inclination angle of molecules relative to the substrate surface equal to 80° and the lower degree of crystallinity compared to the ZnPc film.
AB - In this work, thin films of tetrafluorosubstituted zinc phthalocyanine (ZnPcF4) were deposited by organic molecular beam deposition and studied to reveal the effects of F-substituents on the ZnPcF4 single crystals and thin films structure. A combination of spectral ellipsometry, atomic force microscopy and diffraction techniques has been used to elucidate the structural features and molecular orientation of thin films of ZnPcF4. Structural features of the films grown by co-evaporation of ZnPc and ZnPcF4 (1:1) were also considered. Both ZnPcF4 and ZnPc/ZnPcF4 films have a preferred orientation along (001) plane with inclination angle of molecules relative to the substrate surface equal to 80° and the lower degree of crystallinity compared to the ZnPc film.
KW - Crystal structure
KW - Orientation
KW - Thin films
KW - Zinc phthalocyanines
KW - GASES
KW - orientation
KW - METAL PHTHALOCYANINES
KW - COBALT PHTHALOCYANINE
KW - SPECTRAL PROPERTIES
KW - thin films
KW - TRANSISTORS
KW - crystal structure
KW - F16CUPC
KW - MORPHOLOGY
KW - ELECTRONIC-STRUCTURE
KW - AMBIPOLAR
UR - http://www.scopus.com/inward/record.url?scp=85058657617&partnerID=8YFLogxK
U2 - 10.6060/mhc180794b
DO - 10.6060/mhc180794b
M3 - Article
AN - SCOPUS:85058657617
VL - 11
SP - 304
EP - 311
JO - Macroheterocycles
JF - Macroheterocycles
SN - 1998-9539
IS - 3
ER -
ID: 17886644