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Hydroxylated phosphines as ligands for chalcogenide clusters : Self assembly, transformations and stabilization. / Sokolov, Maxim N.; Anyushin, Alexander V.; Hernandez-Molina, Rita et al.

In: Pure and Applied Chemistry, Vol. 89, No. 3, 01.03.2017, p. 379-392.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, MN, Anyushin, AV, Hernandez-Molina, R, Llusar, R & Basallote, MG 2017, 'Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization', Pure and Applied Chemistry, vol. 89, no. 3, pp. 379-392. https://doi.org/10.1515/pac-2017-0105

APA

Sokolov, M. N., Anyushin, A. V., Hernandez-Molina, R., Llusar, R., & Basallote, M. G. (2017). Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization. Pure and Applied Chemistry, 89(3), 379-392. https://doi.org/10.1515/pac-2017-0105

Vancouver

Sokolov MN, Anyushin AV, Hernandez-Molina R, Llusar R, Basallote MG. Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization. Pure and Applied Chemistry. 2017 Mar 1;89(3):379-392. doi: 10.1515/pac-2017-0105

Author

Sokolov, Maxim N. ; Anyushin, Alexander V. ; Hernandez-Molina, Rita et al. / Hydroxylated phosphines as ligands for chalcogenide clusters : Self assembly, transformations and stabilization. In: Pure and Applied Chemistry. 2017 ; Vol. 89, No. 3. pp. 379-392.

BibTeX

@article{d00bdcfbbb514ed38ccdc624d8d24749,
title = "Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization",
abstract = "This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.",
keywords = "diphosphene, ICPC-21, low coordination, steric protection",
author = "Sokolov, {Maxim N.} and Anyushin, {Alexander V.} and Rita Hernandez-Molina and Rosa Llusar and Basallote, {Manuel G.}",
year = "2017",
month = mar,
day = "1",
doi = "10.1515/pac-2017-0105",
language = "English",
volume = "89",
pages = "379--392",
journal = "Pure and Applied Chemistry",
issn = "0033-4545",
publisher = "Walter de Gruyter GmbH",
number = "3",

}

RIS

TY - JOUR

T1 - Hydroxylated phosphines as ligands for chalcogenide clusters

T2 - Self assembly, transformations and stabilization

AU - Sokolov, Maxim N.

AU - Anyushin, Alexander V.

AU - Hernandez-Molina, Rita

AU - Llusar, Rosa

AU - Basallote, Manuel G.

PY - 2017/3/1

Y1 - 2017/3/1

N2 - This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

AB - This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

KW - diphosphene

KW - ICPC-21

KW - low coordination

KW - steric protection

UR - http://www.scopus.com/inward/record.url?scp=85017302494&partnerID=8YFLogxK

U2 - 10.1515/pac-2017-0105

DO - 10.1515/pac-2017-0105

M3 - Article

AN - SCOPUS:85017302494

VL - 89

SP - 379

EP - 392

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

SN - 0033-4545

IS - 3

ER -

ID: 8967889