Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Hydroxylated phosphines as ligands for chalcogenide clusters : Self assembly, transformations and stabilization. / Sokolov, Maxim N.; Anyushin, Alexander V.; Hernandez-Molina, Rita и др.
в: Pure and Applied Chemistry, Том 89, № 3, 01.03.2017, стр. 379-392.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Hydroxylated phosphines as ligands for chalcogenide clusters
T2 - Self assembly, transformations and stabilization
AU - Sokolov, Maxim N.
AU - Anyushin, Alexander V.
AU - Hernandez-Molina, Rita
AU - Llusar, Rosa
AU - Basallote, Manuel G.
PY - 2017/3/1
Y1 - 2017/3/1
N2 - This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.
AB - This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.
KW - diphosphene
KW - ICPC-21
KW - low coordination
KW - steric protection
UR - http://www.scopus.com/inward/record.url?scp=85017302494&partnerID=8YFLogxK
U2 - 10.1515/pac-2017-0105
DO - 10.1515/pac-2017-0105
M3 - Article
AN - SCOPUS:85017302494
VL - 89
SP - 379
EP - 392
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
SN - 0033-4545
IS - 3
ER -
ID: 8967889