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Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate. / Volostnykh, Marina V.; Mikhaylov, Maxim A.; Sinelshchikova, Anna A. et al.

In: Dalton Transactions, Vol. 48, No. 5, 07.02.2019, p. 1835-1842.

Research output: Contribution to journal › Article › peer-review

Harvard

Volostnykh, MV, Mikhaylov, MA, Sinelshchikova, AA, Kirakosyan, GA, Martynov, AG, Grigoriev, MS, Piryazev, DA, Tsivadze, AY, Sokolov, MN & Gorbunova, YG 2019, 'Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate', Dalton Transactions, vol. 48, no. 5, pp. 1835-1842. https://doi.org/10.1039/c8dt04452j

APA

Volostnykh, M. V., Mikhaylov, M. A., Sinelshchikova, A. A., Kirakosyan, G. A., Martynov, A. G., Grigoriev, M. S., Piryazev, D. A., Tsivadze, A. Y., Sokolov, M. N., & Gorbunova, Y. G. (2019). Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate. Dalton Transactions, 48(5), 1835-1842. https://doi.org/10.1039/c8dt04452j

Vancouver

Volostnykh MV, Mikhaylov MA, Sinelshchikova AA, Kirakosyan GA, Martynov AG, Grigoriev MS et al. Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate. Dalton Transactions. 2019 Feb 7;48(5):1835-1842. doi: 10.1039/c8dt04452j

Author

Volostnykh, Marina V. ; Mikhaylov, Maxim A. ; Sinelshchikova, Anna A. et al. / Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate. In: Dalton Transactions. 2019 ; Vol. 48, No. 5. pp. 1835-1842.

BibTeX

@article{7446d5aa4c99466681103e182fbec7a4,
title = "Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate",
abstract = "Herein, first examples of supramolecular hybrid organic-inorganic cluster-porphyrin [CPn (n = 2, 6)] systems constructed via metal-ligand coordination have been reported. The pyridine end-decorated Mo(ii) halide cluster ((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]), possessing remarkable photophysical properties, was chosen as the inorganic part and A2-type zinc porphyrin 5,15-bis[(p-tolyl)porphyrinato(2-)]zinc was selected as the organic part. The crystal structures of CP2 and CP6 hybrids have been characterised by single crystal X-ray diffraction. The CP2 complex is composed of two zinc porphyrins, coordinated to pyridyl moieties of the same cluster molecule, related by an inversion center. In the case of the CP6 complex, each cluster has three pairs of coordinated symmetrically equivalent zinc porphyrins. Also, the formation of supramolecular hybrid CPn (n = 2, 6) systems was unambiguously demonstrated in solution via NMR and UV-Vis spectroscopy titration and diffusion ordered NMR spectroscopy (DOSY).",
keywords = "TEMPLATE-DIRECTED SYNTHESIS, COMPLEXES, LIGAND, COPPER(II), ADSORPTION",
author = "Volostnykh, {Marina V.} and Mikhaylov, {Maxim A.} and Sinelshchikova, {Anna A.} and Kirakosyan, {Gayane A.} and Martynov, {Alexander G.} and Grigoriev, {Mikhail S.} and Piryazev, {Dmitry A.} and Tsivadze, {Aslan Yu} and Sokolov, {Maxim N.} and Gorbunova, {Yulia G.}",
year = "2019",
month = feb,
day = "7",
doi = "10.1039/c8dt04452j",
language = "English",
volume = "48",
pages = "1835--1842",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "5",

}

RIS

TY - JOUR

T1 - Hybrid organic-inorganic supramolecular systems based on a pyridine end-decorated molybdenum(ii) halide cluster and zinc(ii) porphyrinate

AU - Volostnykh, Marina V.

AU - Mikhaylov, Maxim A.

AU - Sinelshchikova, Anna A.

AU - Kirakosyan, Gayane A.

AU - Martynov, Alexander G.

AU - Grigoriev, Mikhail S.

AU - Piryazev, Dmitry A.

AU - Tsivadze, Aslan Yu

AU - Sokolov, Maxim N.

AU - Gorbunova, Yulia G.

PY - 2019/2/7

Y1 - 2019/2/7

N2 - Herein, first examples of supramolecular hybrid organic-inorganic cluster-porphyrin [CPn (n = 2, 6)] systems constructed via metal-ligand coordination have been reported. The pyridine end-decorated Mo(ii) halide cluster ((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]), possessing remarkable photophysical properties, was chosen as the inorganic part and A2-type zinc porphyrin 5,15-bis[(p-tolyl)porphyrinato(2-)]zinc was selected as the organic part. The crystal structures of CP2 and CP6 hybrids have been characterised by single crystal X-ray diffraction. The CP2 complex is composed of two zinc porphyrins, coordinated to pyridyl moieties of the same cluster molecule, related by an inversion center. In the case of the CP6 complex, each cluster has three pairs of coordinated symmetrically equivalent zinc porphyrins. Also, the formation of supramolecular hybrid CPn (n = 2, 6) systems was unambiguously demonstrated in solution via NMR and UV-Vis spectroscopy titration and diffusion ordered NMR spectroscopy (DOSY).

AB - Herein, first examples of supramolecular hybrid organic-inorganic cluster-porphyrin [CPn (n = 2, 6)] systems constructed via metal-ligand coordination have been reported. The pyridine end-decorated Mo(ii) halide cluster ((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]), possessing remarkable photophysical properties, was chosen as the inorganic part and A2-type zinc porphyrin 5,15-bis[(p-tolyl)porphyrinato(2-)]zinc was selected as the organic part. The crystal structures of CP2 and CP6 hybrids have been characterised by single crystal X-ray diffraction. The CP2 complex is composed of two zinc porphyrins, coordinated to pyridyl moieties of the same cluster molecule, related by an inversion center. In the case of the CP6 complex, each cluster has three pairs of coordinated symmetrically equivalent zinc porphyrins. Also, the formation of supramolecular hybrid CPn (n = 2, 6) systems was unambiguously demonstrated in solution via NMR and UV-Vis spectroscopy titration and diffusion ordered NMR spectroscopy (DOSY).

KW - TEMPLATE-DIRECTED SYNTHESIS

KW - COMPLEXES

KW - LIGAND

KW - COPPER(II)

KW - ADSORPTION

UR - http://www.scopus.com/inward/record.url?scp=85060803981&partnerID=8YFLogxK

U2 - 10.1039/c8dt04452j

DO - 10.1039/c8dt04452j

M3 - Article

C2 - 30648714

AN - SCOPUS:85060803981

VL - 48

SP - 1835

EP - 1842

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 5

ER -

ID: 18488992