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Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin. / Ivanov, Anton A.; Falaise, Clément; Abramov, Pavel A. et al.

In: Chemistry - A European Journal, Vol. 24, No. 51, 12.09.2018, p. 13467-13478.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanov, AA, Falaise, C, Abramov, PA, Shestopalov, MA, Kirakci, K, Lang, K, Moussawi, MA, Sokolov, MN, Naumov, NG, Floquet, S, Landy, D, Haouas, M, Brylev, KA, Mironov, YV, Molard, Y, Cordier, S & Cadot, E 2018, 'Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin', Chemistry - A European Journal, vol. 24, no. 51, pp. 13467-13478. https://doi.org/10.1002/chem.201802102

APA

Ivanov, A. A., Falaise, C., Abramov, P. A., Shestopalov, M. A., Kirakci, K., Lang, K., Moussawi, M. A., Sokolov, M. N., Naumov, N. G., Floquet, S., Landy, D., Haouas, M., Brylev, K. A., Mironov, Y. V., Molard, Y., Cordier, S., & Cadot, E. (2018). Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin. Chemistry - A European Journal, 24(51), 13467-13478. https://doi.org/10.1002/chem.201802102

Vancouver

Ivanov AA, Falaise C, Abramov PA, Shestopalov MA, Kirakci K, Lang K et al. Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin. Chemistry - A European Journal. 2018 Sept 12;24(51):13467-13478. doi: 10.1002/chem.201802102

Author

Ivanov, Anton A. ; Falaise, Clément ; Abramov, Pavel A. et al. / Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin. In: Chemistry - A European Journal. 2018 ; Vol. 24, No. 51. pp. 13467-13478.

BibTeX

@article{7b0a43a101764b618232e50f1e504be3,
title = "Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin",
abstract = "Water-soluble salts of anionic [Re6Q8(CN)6]4- (Q=S, Se, Te) chalcogenide octahedral rhenium clusters react with γ-cyclodextrin (γ-CD) producing a new type of inclusion compounds. Crystal structures determined through single-crystal X-ray diffraction analysis revealed supramolecular host-guest assemblies resulting from close encapsulations of the octahedral cluster within two γ-CDs. Interestingly, nature of the inner Q ligands influences strongly the host-guest conformation. The cluster [Re6S8(CN)6]4- interacts preferentially with the primary faces of the γ-CD while the bulkier clusters [Re6Se8(CN)6]4- and [Re6Te8(CN)6]4- exhibit specific interactions with the secondary faces of the cyclic host. Furthermore, analysis of the crystal packing reveals additional supramolecular interactions that lead to 2D infinite arrangements with [Re6S8(CN)6]4- or to 1D {"}bamboo-like{"} columns with [Re6Se8(CN)6]4- and [Re6Te8(CN)6]4- species. Solution studies, using multinuclear NMR methods, ESI-MS and Isothermal titration calorimetry (ITC) corroborates nicely the solid-state investigations showing that supramolecular pre-organization is retained in aqueous solution even in diluted conditions. Furthermore, ITC analysis showed that host-guest stability increases significantly ongoing from S to Te. At last, we report herein that deep inclusion alters significantly the intrinsic physical-chemical properties of the octahedral clusters, allowing redox tuning and near IR luminescence enhancement.",
keywords = "Cyclodextrin, Electrochemistry, Luminescence, Metal cluster complex, Supramolecular self-assembly, luminescence, electrochemistry, metal cluster complex, supramolecular self-assembly, cyclodextrin, BUILDING-BLOCKS, SINGLET OXYGEN PRODUCTION, CELLULAR INTERNALIZATION, CRYSTAL-STRUCTURES, PHOTOPHYSICAL PROPERTIES, IODIDE CLUSTER, HYBRID MATERIALS, METAL-ORGANIC FRAMEWORKS, RAY CONTRAST AGENT, BETA-CYCLODEXTRIN",
author = "Ivanov, {Anton A.} and Cl{\'e}ment Falaise and Abramov, {Pavel A.} and Shestopalov, {Michael A.} and Kaplan Kirakci and Kamil Lang and Moussawi, {Mhamad A.} and Sokolov, {Maxim N.} and Naumov, {Nikolay G.} and S{\'e}bastien Floquet and David Landy and Mohamed Haouas and Brylev, {Konstantin A.} and Mironov, {Yuri V.} and Yann Molard and St{\'e}phane Cordier and Emmanuel Cadot",
note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2018",
month = sep,
day = "12",
doi = "10.1002/chem.201802102",
language = "English",
volume = "24",
pages = "13467--13478",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "51",

}

RIS

TY - JOUR

T1 - Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin

AU - Ivanov, Anton A.

AU - Falaise, Clément

AU - Abramov, Pavel A.

AU - Shestopalov, Michael A.

AU - Kirakci, Kaplan

AU - Lang, Kamil

AU - Moussawi, Mhamad A.

AU - Sokolov, Maxim N.

AU - Naumov, Nikolay G.

AU - Floquet, Sébastien

AU - Landy, David

AU - Haouas, Mohamed

AU - Brylev, Konstantin A.

AU - Mironov, Yuri V.

AU - Molard, Yann

AU - Cordier, Stéphane

AU - Cadot, Emmanuel

N1 - Publisher Copyright: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2018/9/12

Y1 - 2018/9/12

N2 - Water-soluble salts of anionic [Re6Q8(CN)6]4- (Q=S, Se, Te) chalcogenide octahedral rhenium clusters react with γ-cyclodextrin (γ-CD) producing a new type of inclusion compounds. Crystal structures determined through single-crystal X-ray diffraction analysis revealed supramolecular host-guest assemblies resulting from close encapsulations of the octahedral cluster within two γ-CDs. Interestingly, nature of the inner Q ligands influences strongly the host-guest conformation. The cluster [Re6S8(CN)6]4- interacts preferentially with the primary faces of the γ-CD while the bulkier clusters [Re6Se8(CN)6]4- and [Re6Te8(CN)6]4- exhibit specific interactions with the secondary faces of the cyclic host. Furthermore, analysis of the crystal packing reveals additional supramolecular interactions that lead to 2D infinite arrangements with [Re6S8(CN)6]4- or to 1D "bamboo-like" columns with [Re6Se8(CN)6]4- and [Re6Te8(CN)6]4- species. Solution studies, using multinuclear NMR methods, ESI-MS and Isothermal titration calorimetry (ITC) corroborates nicely the solid-state investigations showing that supramolecular pre-organization is retained in aqueous solution even in diluted conditions. Furthermore, ITC analysis showed that host-guest stability increases significantly ongoing from S to Te. At last, we report herein that deep inclusion alters significantly the intrinsic physical-chemical properties of the octahedral clusters, allowing redox tuning and near IR luminescence enhancement.

AB - Water-soluble salts of anionic [Re6Q8(CN)6]4- (Q=S, Se, Te) chalcogenide octahedral rhenium clusters react with γ-cyclodextrin (γ-CD) producing a new type of inclusion compounds. Crystal structures determined through single-crystal X-ray diffraction analysis revealed supramolecular host-guest assemblies resulting from close encapsulations of the octahedral cluster within two γ-CDs. Interestingly, nature of the inner Q ligands influences strongly the host-guest conformation. The cluster [Re6S8(CN)6]4- interacts preferentially with the primary faces of the γ-CD while the bulkier clusters [Re6Se8(CN)6]4- and [Re6Te8(CN)6]4- exhibit specific interactions with the secondary faces of the cyclic host. Furthermore, analysis of the crystal packing reveals additional supramolecular interactions that lead to 2D infinite arrangements with [Re6S8(CN)6]4- or to 1D "bamboo-like" columns with [Re6Se8(CN)6]4- and [Re6Te8(CN)6]4- species. Solution studies, using multinuclear NMR methods, ESI-MS and Isothermal titration calorimetry (ITC) corroborates nicely the solid-state investigations showing that supramolecular pre-organization is retained in aqueous solution even in diluted conditions. Furthermore, ITC analysis showed that host-guest stability increases significantly ongoing from S to Te. At last, we report herein that deep inclusion alters significantly the intrinsic physical-chemical properties of the octahedral clusters, allowing redox tuning and near IR luminescence enhancement.

KW - Cyclodextrin

KW - Electrochemistry

KW - Luminescence

KW - Metal cluster complex

KW - Supramolecular self-assembly

KW - luminescence

KW - electrochemistry

KW - metal cluster complex

KW - supramolecular self-assembly

KW - cyclodextrin

KW - BUILDING-BLOCKS

KW - SINGLET OXYGEN PRODUCTION

KW - CELLULAR INTERNALIZATION

KW - CRYSTAL-STRUCTURES

KW - PHOTOPHYSICAL PROPERTIES

KW - IODIDE CLUSTER

KW - HYBRID MATERIALS

KW - METAL-ORGANIC FRAMEWORKS

KW - RAY CONTRAST AGENT

KW - BETA-CYCLODEXTRIN

UR - http://www.scopus.com/inward/record.url?scp=85051032384&partnerID=8YFLogxK

U2 - 10.1002/chem.201802102

DO - 10.1002/chem.201802102

M3 - Article

C2 - 29894019

AN - SCOPUS:85051032384

VL - 24

SP - 13467

EP - 13478

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 51

ER -

ID: 16063914