Research output: Contribution to journal › Article › peer-review
Hexafluorosilicates of cobalt(II) complexes with dimethylsulfoxide and dimethylformamide. / Cherkasova, T. G.; Bagryanskaya, I. Yu; Pervukhina, N. V. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 62, No. 6, 01.06.2017, p. 760-765.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Hexafluorosilicates of cobalt(II) complexes with dimethylsulfoxide and dimethylformamide
AU - Cherkasova, T. G.
AU - Bagryanskaya, I. Yu
AU - Pervukhina, N. V.
AU - Kurat’eva, N. V.
AU - Medvedev, V. V.
AU - Tatarinova, E. S.
AU - Cherkasova, E. V.
PY - 2017/6/1
Y1 - 2017/6/1
N2 - New double complexes [Co(DMSO)6][SiF6] ⋅ 2H2O (I) and [Co(DMF)3(H2O)3][SiF6] ⋅ DMF (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals of complex I belong to the tetragonal symmetry system, space group R3̄, Z = 3, a = 11.8232(3) Å, c = 18.4699(5) Å, V = 2235.97(10) Å3, ρcalc = 1.573 g/cm3. Crystals of complex II are triclinic, space group P1̄, Z = 2, a = 8.6264(4) Å, b = 10.1419(4) Å, c = 13.9657(6) Å, α = 100.847(2)°, β = 98.549(2)°, γ = 93.479(2)°, V = 1181.71(9) Å3, ρcalc = 1.539 g/cm3.
AB - New double complexes [Co(DMSO)6][SiF6] ⋅ 2H2O (I) and [Co(DMF)3(H2O)3][SiF6] ⋅ DMF (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals of complex I belong to the tetragonal symmetry system, space group R3̄, Z = 3, a = 11.8232(3) Å, c = 18.4699(5) Å, V = 2235.97(10) Å3, ρcalc = 1.573 g/cm3. Crystals of complex II are triclinic, space group P1̄, Z = 2, a = 8.6264(4) Å, b = 10.1419(4) Å, c = 13.9657(6) Å, α = 100.847(2)°, β = 98.549(2)°, γ = 93.479(2)°, V = 1181.71(9) Å3, ρcalc = 1.539 g/cm3.
KW - CRYSTAL-STRUCTURE
UR - http://www.scopus.com/inward/record.url?scp=85021672589&partnerID=8YFLogxK
U2 - 10.1134/S003602361706002X
DO - 10.1134/S003602361706002X
M3 - Article
AN - SCOPUS:85021672589
VL - 62
SP - 760
EP - 765
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
SN - 0036-0236
IS - 6
ER -
ID: 10096688