Standard

Hexaazide octahedral molybdenum cluster complexes : Synthesis, properties and the evidence of hydrolysis. / Vorotnikov, Yuri A.; Efremova, Olga A.; Novozhilov, Igor N. et al.

In: Journal of Molecular Structure, Vol. 1134, 15.04.2017, p. 237-243.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorotnikov, YA, Efremova, OA, Novozhilov, IN, Yanshole, VV, Kuratieva, NV, Brylev, KA, Kitamura, N, Mironov, YV & Shestopalov, MA 2017, 'Hexaazide octahedral molybdenum cluster complexes: Synthesis, properties and the evidence of hydrolysis', Journal of Molecular Structure, vol. 1134, pp. 237-243. https://doi.org/10.1016/j.molstruc.2016.12.052

APA

Vorotnikov, Y. A., Efremova, O. A., Novozhilov, I. N., Yanshole, V. V., Kuratieva, N. V., Brylev, K. A., Kitamura, N., Mironov, Y. V., & Shestopalov, M. A. (2017). Hexaazide octahedral molybdenum cluster complexes: Synthesis, properties and the evidence of hydrolysis. Journal of Molecular Structure, 1134, 237-243. https://doi.org/10.1016/j.molstruc.2016.12.052

Vancouver

Vorotnikov YA, Efremova OA, Novozhilov IN, Yanshole VV, Kuratieva NV, Brylev KA et al. Hexaazide octahedral molybdenum cluster complexes: Synthesis, properties and the evidence of hydrolysis. Journal of Molecular Structure. 2017 Apr 15;1134:237-243. doi: 10.1016/j.molstruc.2016.12.052

Author

Vorotnikov, Yuri A. ; Efremova, Olga A. ; Novozhilov, Igor N. et al. / Hexaazide octahedral molybdenum cluster complexes : Synthesis, properties and the evidence of hydrolysis. In: Journal of Molecular Structure. 2017 ; Vol. 1134. pp. 237-243.

BibTeX

@article{75d808e3b883471d9eef82868ad7ebd9,
title = "Hexaazide octahedral molybdenum cluster complexes: Synthesis, properties and the evidence of hydrolysis",
abstract = "This article reports the synthesis, crystal structure of new molybdenum hexaazide cluster complex (nBu4N)2[{Mo6I8}(N3)6] (3) and comparison of its photophysical and electrochemical properties to those of earlier reported analogues (nBu4N)2[{Mo6X8}(N3)6] (X = Cl, Br). Additionally, the dimerisation of 3 as a result of hydrolysis was revealed by mass spectrometry and single crystal X-Ray diffraction. Indeed, the structurally characterised compound (nBu4N)4[({Mo6I8}(N3)5)2O] represents the first example of oxo-bridged dimer of octahedral molybdenum clusters complexes.",
keywords = "Crystal structure, ESI mass spectrometry, Hydrolysis, Luminescence, Octahedral molybdenum clusters, UNIT, ONE-POT SYNTHESIS, CRYSTAL-STRUCTURE, AZIDE, BR, NANOPARTICLES, HEXANUCLEAR MOLYBDENUM, LUMINESCENCE, LIGANDS, REDOX",
author = "Vorotnikov, {Yuri A.} and Efremova, {Olga A.} and Novozhilov, {Igor N.} and Yanshole, {Vadim V.} and Kuratieva, {Natalia V.} and Brylev, {Konstantin A.} and Noboru Kitamura and Mironov, {Yuri V.} and Shestopalov, {Michael A.}",
year = "2017",
month = apr,
day = "15",
doi = "10.1016/j.molstruc.2016.12.052",
language = "English",
volume = "1134",
pages = "237--243",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Hexaazide octahedral molybdenum cluster complexes

T2 - Synthesis, properties and the evidence of hydrolysis

AU - Vorotnikov, Yuri A.

AU - Efremova, Olga A.

AU - Novozhilov, Igor N.

AU - Yanshole, Vadim V.

AU - Kuratieva, Natalia V.

AU - Brylev, Konstantin A.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

AU - Shestopalov, Michael A.

PY - 2017/4/15

Y1 - 2017/4/15

N2 - This article reports the synthesis, crystal structure of new molybdenum hexaazide cluster complex (nBu4N)2[{Mo6I8}(N3)6] (3) and comparison of its photophysical and electrochemical properties to those of earlier reported analogues (nBu4N)2[{Mo6X8}(N3)6] (X = Cl, Br). Additionally, the dimerisation of 3 as a result of hydrolysis was revealed by mass spectrometry and single crystal X-Ray diffraction. Indeed, the structurally characterised compound (nBu4N)4[({Mo6I8}(N3)5)2O] represents the first example of oxo-bridged dimer of octahedral molybdenum clusters complexes.

AB - This article reports the synthesis, crystal structure of new molybdenum hexaazide cluster complex (nBu4N)2[{Mo6I8}(N3)6] (3) and comparison of its photophysical and electrochemical properties to those of earlier reported analogues (nBu4N)2[{Mo6X8}(N3)6] (X = Cl, Br). Additionally, the dimerisation of 3 as a result of hydrolysis was revealed by mass spectrometry and single crystal X-Ray diffraction. Indeed, the structurally characterised compound (nBu4N)4[({Mo6I8}(N3)5)2O] represents the first example of oxo-bridged dimer of octahedral molybdenum clusters complexes.

KW - Crystal structure

KW - ESI mass spectrometry

KW - Hydrolysis

KW - Luminescence

KW - Octahedral molybdenum clusters

KW - UNIT

KW - ONE-POT SYNTHESIS

KW - CRYSTAL-STRUCTURE

KW - AZIDE

KW - BR

KW - NANOPARTICLES

KW - HEXANUCLEAR MOLYBDENUM

KW - LUMINESCENCE

KW - LIGANDS

KW - REDOX

UR - http://www.scopus.com/inward/record.url?scp=85008145408&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2016.12.052

DO - 10.1016/j.molstruc.2016.12.052

M3 - Article

AN - SCOPUS:85008145408

VL - 1134

SP - 237

EP - 243

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 10041055