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Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems. / Kostin, Gennadiy A.; Borodin, Alexander O.; Kuratieva, Natalia V. et al.

In: Inorganica Chimica Acta, Vol. 457, 01.03.2017, p. 145-149.

Research output: Contribution to journal › Article › peer-review

Harvard

Kostin, GA, Borodin, AO, Kuratieva, NV, Filatov, EY & Plyusnin, PE 2017, 'Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems', Inorganica Chimica Acta, vol. 457, pp. 145-149. https://doi.org/10.1016/j.ica.2016.12.016

APA

Kostin, G. A., Borodin, A. O., Kuratieva, N. V., Filatov, E. Y., & Plyusnin, P. E. (2017). Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems. Inorganica Chimica Acta, 457, 145-149. https://doi.org/10.1016/j.ica.2016.12.016

Vancouver

Kostin GA, Borodin AO, Kuratieva NV, Filatov EY, Plyusnin PE. Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems. Inorganica Chimica Acta. 2017 Mar 1;457:145-149. doi: 10.1016/j.ica.2016.12.016

Author

Kostin, Gennadiy A. ; Borodin, Alexander O. ; Kuratieva, Natalia V. et al. / Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems. In: Inorganica Chimica Acta. 2017 ; Vol. 457. pp. 145-149.

BibTeX

@article{1f42c7f234274a60aeadd887b0ba853a,
title = "Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems",
abstract = "An exchange reaction between Ba[RuNO(NO2)4OH] and cobalt (nickel) sulphate results in the formation of heterometallic [RuNO(NO2)4OHM(H2O)3] complexes with bridging (N,O)-NO2 and μ-(OH) ligands. The crystal structures of both complexes are determined. Thermal decomposition in H2/He atmosphere leads to the formation of solid solutions of the metals. In the case of the nickel complex, the compositions of the prepared solid solutions are in the miscibility gap. In oxygen atmosphere mixed oxide systems NiO–RuO2 and Co3O4–RuO2 are formed in temperature interval from 400 to 600 °C. At temperatures from 900 to 1000 °C spinel-type phase Co2.1Ru0.9O4 is formed.",
keywords = "OXYGEN EVOLUTION REACTION, CRYSTAL-STRUCTURES, MISCIBILITY GAP, CATALYSTS, RUTHENIUM, NANOPARTICLES, COBALT, ELECTROCATALYSTS, DECOMPOSITION, THERMOLYSIS",
author = "Kostin, {Gennadiy A.} and Borodin, {Alexander O.} and Kuratieva, {Natalia V.} and Filatov, {Evgeny Yu} and Plyusnin, {Pavel E.}",
year = "2017",
month = mar,
day = "1",
doi = "10.1016/j.ica.2016.12.016",
language = "English",
volume = "457",
pages = "145--149",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Heterometallic complexes [RuNO(NO2)4OHM(H2O)3] (M = Co, Ni) as the precursors for thermal preparation of heterometallic systems

AU - Kostin, Gennadiy A.

AU - Borodin, Alexander O.

AU - Kuratieva, Natalia V.

AU - Filatov, Evgeny Yu

AU - Plyusnin, Pavel E.

PY - 2017/3/1

Y1 - 2017/3/1

N2 - An exchange reaction between Ba[RuNO(NO2)4OH] and cobalt (nickel) sulphate results in the formation of heterometallic [RuNO(NO2)4OHM(H2O)3] complexes with bridging (N,O)-NO2 and μ-(OH) ligands. The crystal structures of both complexes are determined. Thermal decomposition in H2/He atmosphere leads to the formation of solid solutions of the metals. In the case of the nickel complex, the compositions of the prepared solid solutions are in the miscibility gap. In oxygen atmosphere mixed oxide systems NiO–RuO2 and Co3O4–RuO2 are formed in temperature interval from 400 to 600 °C. At temperatures from 900 to 1000 °C spinel-type phase Co2.1Ru0.9O4 is formed.

AB - An exchange reaction between Ba[RuNO(NO2)4OH] and cobalt (nickel) sulphate results in the formation of heterometallic [RuNO(NO2)4OHM(H2O)3] complexes with bridging (N,O)-NO2 and μ-(OH) ligands. The crystal structures of both complexes are determined. Thermal decomposition in H2/He atmosphere leads to the formation of solid solutions of the metals. In the case of the nickel complex, the compositions of the prepared solid solutions are in the miscibility gap. In oxygen atmosphere mixed oxide systems NiO–RuO2 and Co3O4–RuO2 are formed in temperature interval from 400 to 600 °C. At temperatures from 900 to 1000 °C spinel-type phase Co2.1Ru0.9O4 is formed.

KW - OXYGEN EVOLUTION REACTION

KW - CRYSTAL-STRUCTURES

KW - MISCIBILITY GAP

KW - CATALYSTS

KW - RUTHENIUM

KW - NANOPARTICLES

KW - COBALT

KW - ELECTROCATALYSTS

KW - DECOMPOSITION

KW - THERMOLYSIS

UR - http://www.scopus.com/inward/record.url?scp=85007125171&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2016.12.016

DO - 10.1016/j.ica.2016.12.016

M3 - Article

AN - SCOPUS:85007125171

VL - 457

SP - 145

EP - 149

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 10317258