Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks

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Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S. et al.

In: CrystEngComm, Vol. 21, No. 5, 07.02.2019, p. 850-856.

Research output: Contribution to journal › Article › peer-review

Author

Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Novikov, Alexander S. et al. / Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks. In: CrystEngComm. 2019 ; Vol. 21, No. 5. pp. 850-856.

BibTeX

@article{05a63585817c475ca1f5f67e92a1bdca,

title = "Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks",

abstract = "In the reactions between the mononuclear [SbBr6]3- species, Br2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol-1).",

keywords = "CRYSTAL-STRUCTURE, NONCOVALENT INTERACTIONS, ANIONS, IODIDE, NONABROMOANTIMONATE(V), COMPLEXES, BROMINE, CENTERS, NETWORK",

author = "Adonin, {Sergey A.} and Bondarenko, {Mikhail A.} and Novikov, {Alexander S.} and Abramov, {Pavel A.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2019",

month = feb,

day = "7",

doi = "10.1039/c8ce01944d",

language = "English",

volume = "21",

pages = "850--856",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "5",

}

RIS

TY - JOUR

T1 - Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks

AU - Adonin, Sergey A.

AU - Bondarenko, Mikhail A.

AU - Novikov, Alexander S.

AU - Abramov, Pavel A.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/2/7

Y1 - 2019/2/7

N2 - In the reactions between the mononuclear [SbBr6]3- species, Br2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol-1).

AB - In the reactions between the mononuclear [SbBr6]3- species, Br2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol-1).

KW - CRYSTAL-STRUCTURE

KW - NONCOVALENT INTERACTIONS

KW - ANIONS

KW - IODIDE

KW - NONABROMOANTIMONATE(V)

KW - COMPLEXES

KW - BROMINE

KW - CENTERS

KW - NETWORK

UR - http://www.scopus.com/inward/record.url?scp=85060811692&partnerID=8YFLogxK

U2 - 10.1039/c8ce01944d

DO - 10.1039/c8ce01944d

M3 - Article

AN - SCOPUS:85060811692

VL - 21

SP - 850

EP - 856

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 5

ER -

ID: 18485293