Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S. и др.
в: CrystEngComm, Том 21, № 5, 07.02.2019, стр. 850-856.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Halogen bonding-assisted assembly of bromoantimonate(v) and polybromide-bromoantimonate-based frameworks
AU - Adonin, Sergey A.
AU - Bondarenko, Mikhail A.
AU - Novikov, Alexander S.
AU - Abramov, Pavel A.
AU - Plyusnin, Pavel E.
AU - Sokolov, Maxim N.
AU - Fedin, Vladimir P.
PY - 2019/2/7
Y1 - 2019/2/7
N2 - In the reactions between the mononuclear [SbBr6]3- species, Br2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol-1).
AB - In the reactions between the mononuclear [SbBr6]3- species, Br2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol-1).
KW - CRYSTAL-STRUCTURE
KW - NONCOVALENT INTERACTIONS
KW - ANIONS
KW - IODIDE
KW - NONABROMOANTIMONATE(V)
KW - COMPLEXES
KW - BROMINE
KW - CENTERS
KW - NETWORK
UR - http://www.scopus.com/inward/record.url?scp=85060811692&partnerID=8YFLogxK
U2 - 10.1039/c8ce01944d
DO - 10.1039/c8ce01944d
M3 - Article
AN - SCOPUS:85060811692
VL - 21
SP - 850
EP - 856
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 5
ER -
ID: 18485293