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From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts. / Kibis, Lidiya S.; Svintsitskiy, Dmitry A.; Derevyannikova, Elizaveta A. et al.

In: Applied Surface Science, Vol. 493, 01.11.2019, p. 1055-1066.

Research output: Contribution to journal › Article › peer-review

Harvard

Kibis, LS, Svintsitskiy, DA, Derevyannikova, EA, Kardash, TY, Slavinskaya, EM, Stonkus, OA, Svetlichnyi, VA & Boronin, AI 2019, 'From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts', Applied Surface Science, vol. 493, pp. 1055-1066. https://doi.org/10.1016/j.apsusc.2019.07.043

APA

Kibis, L. S., Svintsitskiy, D. A., Derevyannikova, E. A., Kardash, T. Y., Slavinskaya, E. M., Stonkus, O. A., Svetlichnyi, V. A., & Boronin, A. I. (2019). From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts. Applied Surface Science, 493, 1055-1066. https://doi.org/10.1016/j.apsusc.2019.07.043

Vancouver

Kibis LS, Svintsitskiy DA, Derevyannikova EA, Kardash TY, Slavinskaya EM, Stonkus OA et al. From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts. Applied Surface Science. 2019 Nov 1;493:1055-1066. doi: 10.1016/j.apsusc.2019.07.043

Author

Kibis, Lidiya S. ; Svintsitskiy, Dmitry A. ; Derevyannikova, Elizaveta A. et al. / From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts. In: Applied Surface Science. 2019 ; Vol. 493. pp. 1055-1066.

BibTeX

@article{5c2d4ee38423412f9ef0392b2c953dc8,
title = "From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts",
abstract = "For supported catalysts based on highly-priced noble metals the maximum catalytic efficiency per metal atom is highly desired. In this work, Rh-doped CeO2 systems were studied as potential catalysts for low-temperature NO reduction by CO. Thermal and redox treatments allowed varying the Rh oxidation state and the size of rhodium particles formed on CeO2 surface. By combination of surface and bulk sensitive physicochemical techniques the structure-activity correlations were established. Initial Rh-doped CeO2 catalysts contained Rh3+ species ionically dispersed in CeO2 lattice and showed activity in CO + NO reaction already at room temperature. Reduction treatment of Rh3+-CeO2 catalysts resulted in the formation of rhodium particles of ~1 nm in size on the reduced ceria surface. The catalytic characteristics of the initial and reduced samples were comparable, indicating the close nature of the active sites and their dynamic formation directly under the reaction conditions. Calcination of Rh3+-CeO2 sample at T > 800°С resulted in formation of rhodium oxide nanoparticles on the ceria surface. Such Rh2О3/CeO2 catalysts showed activity only at T > 200°С. Their activity in 100–200 °C temperature range could be substantially improved by the reduction treatment. The oxygen vacancies of СеО2 and small Rhn 0 particles proved to be essential for the catalytic activity below 100 °C.",
keywords = "Ceria, N selectivity, Nitrogen oxides, Rhodium catalysts, THERMAL-STABILITY, RHODIUM, MECHANISM, METAL-SUPPORT INTERACTION, MIXED-OXIDE, N-2 selectivity, ION SUBSTITUTED CEO2, REDUCTION, CERIA, N2O DECOMPOSITION, IN-SITU",
author = "Kibis, {Lidiya S.} and Svintsitskiy, {Dmitry A.} and Derevyannikova, {Elizaveta A.} and Kardash, {Tatyana Yu} and Slavinskaya, {Elena M.} and Stonkus, {Olga A.} and Svetlichnyi, {Valery A.} and Boronin, {Andrei I.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = nov,
day = "1",
doi = "10.1016/j.apsusc.2019.07.043",
language = "English",
volume = "493",
pages = "1055--1066",
journal = "Applied Surface Science",
issn = "0169-4332",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - From highly dispersed Rh3+ to nanoclusters and nanoparticles: Probing the low-temperature NO+CO activity of Rh-doped CeO2 catalysts

AU - Kibis, Lidiya S.

AU - Svintsitskiy, Dmitry A.

AU - Derevyannikova, Elizaveta A.

AU - Kardash, Tatyana Yu

AU - Slavinskaya, Elena M.

AU - Stonkus, Olga A.

AU - Svetlichnyi, Valery A.

AU - Boronin, Andrei I.

N1 - Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - For supported catalysts based on highly-priced noble metals the maximum catalytic efficiency per metal atom is highly desired. In this work, Rh-doped CeO2 systems were studied as potential catalysts for low-temperature NO reduction by CO. Thermal and redox treatments allowed varying the Rh oxidation state and the size of rhodium particles formed on CeO2 surface. By combination of surface and bulk sensitive physicochemical techniques the structure-activity correlations were established. Initial Rh-doped CeO2 catalysts contained Rh3+ species ionically dispersed in CeO2 lattice and showed activity in CO + NO reaction already at room temperature. Reduction treatment of Rh3+-CeO2 catalysts resulted in the formation of rhodium particles of ~1 nm in size on the reduced ceria surface. The catalytic characteristics of the initial and reduced samples were comparable, indicating the close nature of the active sites and their dynamic formation directly under the reaction conditions. Calcination of Rh3+-CeO2 sample at T > 800°С resulted in formation of rhodium oxide nanoparticles on the ceria surface. Such Rh2О3/CeO2 catalysts showed activity only at T > 200°С. Their activity in 100–200 °C temperature range could be substantially improved by the reduction treatment. The oxygen vacancies of СеО2 and small Rhn 0 particles proved to be essential for the catalytic activity below 100 °C.

AB - For supported catalysts based on highly-priced noble metals the maximum catalytic efficiency per metal atom is highly desired. In this work, Rh-doped CeO2 systems were studied as potential catalysts for low-temperature NO reduction by CO. Thermal and redox treatments allowed varying the Rh oxidation state and the size of rhodium particles formed on CeO2 surface. By combination of surface and bulk sensitive physicochemical techniques the structure-activity correlations were established. Initial Rh-doped CeO2 catalysts contained Rh3+ species ionically dispersed in CeO2 lattice and showed activity in CO + NO reaction already at room temperature. Reduction treatment of Rh3+-CeO2 catalysts resulted in the formation of rhodium particles of ~1 nm in size on the reduced ceria surface. The catalytic characteristics of the initial and reduced samples were comparable, indicating the close nature of the active sites and their dynamic formation directly under the reaction conditions. Calcination of Rh3+-CeO2 sample at T > 800°С resulted in formation of rhodium oxide nanoparticles on the ceria surface. Such Rh2О3/CeO2 catalysts showed activity only at T > 200°С. Their activity in 100–200 °C temperature range could be substantially improved by the reduction treatment. The oxygen vacancies of СеО2 and small Rhn 0 particles proved to be essential for the catalytic activity below 100 °C.

KW - Ceria

KW - N selectivity

KW - Nitrogen oxides

KW - Rhodium catalysts

KW - THERMAL-STABILITY

KW - RHODIUM

KW - MECHANISM

KW - METAL-SUPPORT INTERACTION

KW - MIXED-OXIDE

KW - N-2 selectivity

KW - ION SUBSTITUTED CEO2

KW - REDUCTION

KW - CERIA

KW - N2O DECOMPOSITION

KW - IN-SITU

UR - http://www.scopus.com/inward/record.url?scp=85069737954&partnerID=8YFLogxK

U2 - 10.1016/j.apsusc.2019.07.043

DO - 10.1016/j.apsusc.2019.07.043

M3 - Article

AN - SCOPUS:85069737954

VL - 493

SP - 1055

EP - 1066

JO - Applied Surface Science

JF - Applied Surface Science

SN - 0169-4332

ER -

ID: 21045182