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Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations. / Gayfulin, Ya M.; Piryazev, D. A.; Mironov, Yu V. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 6, 01.06.2017, p. 364-367.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Piryazev, DA, Mironov, YV & Naumov, NG 2017, 'Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 6, pp. 364-367. https://doi.org/10.1134/S107032841706001X

APA

Gayfulin, Y. M., Piryazev, D. A., Mironov, Y. V., & Naumov, N. G. (2017). Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(6), 364-367. https://doi.org/10.1134/S107032841706001X

Vancouver

Gayfulin YM, Piryazev DA, Mironov YV, Naumov NG. Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 Jun 1;43(6):364-367. doi: 10.1134/S107032841706001X

Author

Gayfulin, Ya M. ; Piryazev, D. A. ; Mironov, Yu V. et al. / Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Vol. 43, No. 6. pp. 364-367.

BibTeX

@article{95ceb40f0b5049f0a4a5d302ea7230a0,
title = "Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations",
abstract = "A new coordination polymer, [Cd(NH3)4]2{Cd[Re3Mo3S8(CN)6]}·1.5H2O (I), was prepared by the reaction between solutions of Cd(CH3COO)2 · 2H2O in aqueous ammonia and CaK4[Re3Mo3S8(CN)6] · 8H2O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) {\AA} (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH3 molecules is accompanied by sample amorphization.",
keywords = "cluster complex, coordination polymer, rhenium, structure, thermal stability, PRUSSIAN BLUE ANALOGS, SEPARATIONS, CATALYSIS, METAL-ORGANIC FRAMEWORKS, COMPLEXES, OPPORTUNITIES",
author = "Gayfulin, {Ya M.} and Piryazev, {D. A.} and Mironov, {Yu V.} and Naumov, {N. G.}",
year = "2017",
month = jun,
day = "1",
doi = "10.1134/S107032841706001X",
language = "English",
volume = "43",
pages = "364--367",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "6",

}

RIS

TY - JOUR

T1 - Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations

AU - Gayfulin, Ya M.

AU - Piryazev, D. A.

AU - Mironov, Yu V.

AU - Naumov, N. G.

PY - 2017/6/1

Y1 - 2017/6/1

N2 - A new coordination polymer, [Cd(NH3)4]2{Cd[Re3Mo3S8(CN)6]}·1.5H2O (I), was prepared by the reaction between solutions of Cd(CH3COO)2 · 2H2O in aqueous ammonia and CaK4[Re3Mo3S8(CN)6] · 8H2O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) Å (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH3 molecules is accompanied by sample amorphization.

AB - A new coordination polymer, [Cd(NH3)4]2{Cd[Re3Mo3S8(CN)6]}·1.5H2O (I), was prepared by the reaction between solutions of Cd(CH3COO)2 · 2H2O in aqueous ammonia and CaK4[Re3Mo3S8(CN)6] · 8H2O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) Å (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH3 molecules is accompanied by sample amorphization.

KW - cluster complex

KW - coordination polymer

KW - rhenium

KW - structure

KW - thermal stability

KW - PRUSSIAN BLUE ANALOGS

KW - SEPARATIONS

KW - CATALYSIS

KW - METAL-ORGANIC FRAMEWORKS

KW - COMPLEXES

KW - OPPORTUNITIES

UR - http://www.scopus.com/inward/record.url?scp=85020645251&partnerID=8YFLogxK

U2 - 10.1134/S107032841706001X

DO - 10.1134/S107032841706001X

M3 - Article

AN - SCOPUS:85020645251

VL - 43

SP - 364

EP - 367

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 6

ER -

ID: 10184425