Research output: Contribution to journal › Article › peer-review
Formation and study of p–i–n structures based on two-phase hydrogenated silicon with a germanium layer in the i-type region. / Krivyakin, G. K.; Volodin, V. A.; Shklyaev, A. A. et al.
In: Semiconductors, Vol. 51, No. 10, 01.10.2017, p. 1370-1376.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Formation and study of p–i–n structures based on two-phase hydrogenated silicon with a germanium layer in the i-type region
AU - Krivyakin, G. K.
AU - Volodin, V. A.
AU - Shklyaev, A. A.
AU - Mortet, V.
AU - More-Chevalier, J.
AU - Ashcheulov, P.
AU - Remes, Z.
AU - Stuchliková, T. H.
AU - Stuchlik, J.
PY - 2017/10/1
Y1 - 2017/10/1
N2 - Four pairs of p–i–n structures based on polymorphous Si:H (pm-Si:H) are fabricated by the method of plasma-enhanced chemical vapor deposition. The structures in each pair are grown on the same substrate so that one of them does not contain Ge in the i-type layer while the other structure contains Ge deposited by molecular-beam epitaxy as a layer with a thickness of 10 nm. The pair differ from one another in terms of the substrate temperature during Ge deposition; these temperatures are 300, 350, 400, and 450°C. The data of electron microscopy show that the structures formed at 300°C contain Ge nanocrystals (nc-Ge) nucleated at nanocrystalline inclusions at the pm-Si:H surface. The nc-Ge concentration increases as the temperature is raised. The study of the current–voltage characteristics show that the presence of Ge in the i-type layer decreases the density of the short-circuit current in p–i–n structures when they are used as solar cells, whereas these layers give rise to an increase in current at a reverse bias under illumination. The obtained results are consistent with known data for structures with Ge clusters in Si; according to these data, Ge clusters increase the coefficient of light absorption but they also increase the rate of charge-carrier recombination.
AB - Four pairs of p–i–n structures based on polymorphous Si:H (pm-Si:H) are fabricated by the method of plasma-enhanced chemical vapor deposition. The structures in each pair are grown on the same substrate so that one of them does not contain Ge in the i-type layer while the other structure contains Ge deposited by molecular-beam epitaxy as a layer with a thickness of 10 nm. The pair differ from one another in terms of the substrate temperature during Ge deposition; these temperatures are 300, 350, 400, and 450°C. The data of electron microscopy show that the structures formed at 300°C contain Ge nanocrystals (nc-Ge) nucleated at nanocrystalline inclusions at the pm-Si:H surface. The nc-Ge concentration increases as the temperature is raised. The study of the current–voltage characteristics show that the presence of Ge in the i-type layer decreases the density of the short-circuit current in p–i–n structures when they are used as solar cells, whereas these layers give rise to an increase in current at a reverse bias under illumination. The obtained results are consistent with known data for structures with Ge clusters in Si; according to these data, Ge clusters increase the coefficient of light absorption but they also increase the rate of charge-carrier recombination.
KW - VOLUME FRACTION
KW - QUANTUM DOTS
KW - SOLAR-CELLS
KW - GE ISLANDS
KW - FILMS
KW - PHASE
KW - RAMAN
KW - PHOTOLUMINESCENCE
KW - PHOTOCONDUCTIVITY
KW - NANOCRYSTALS
UR - http://www.scopus.com/inward/record.url?scp=85030973686&partnerID=8YFLogxK
U2 - 10.1134/S1063782617100128
DO - 10.1134/S1063782617100128
M3 - Article
AN - SCOPUS:85030973686
VL - 51
SP - 1370
EP - 1376
JO - Semiconductors
JF - Semiconductors
SN - 1063-7826
IS - 10
ER -
ID: 9894238