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Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. / Fedyushin, Pavel A.; Gurskaya, Larisa Yu; Пантелеева, Елена Валерьевна et al.

In: FLUORINE NOTES, Vol. 123, No. 2, 2019, p. 7-8.

Research output: Contribution to journal › Article › peer-review

Harvard

Fedyushin, PA, Gurskaya, LY, Пантелеева, ЕВ, Кощеев, БВ, Maksimov, AM, Рыбалова, ТВ, Зайцева, ЕВ & Третьяков, ЕВ 2019, 'Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides', FLUORINE NOTES, vol. 123, no. 2, pp. 7-8. https://doi.org/10.17677/fn20714807.2019.02.04

APA

Fedyushin, P. A., Gurskaya, L. Y., Пантелеева, Е. В., Кощеев, Б. В., Maksimov, A. M., Рыбалова, Т. В., Зайцева, Е. В., & Третьяков, Е. В. (2019). Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. FLUORINE NOTES, 123(2), 7-8. https://doi.org/10.17677/fn20714807.2019.02.04

Vancouver

Fedyushin PA, Gurskaya LY, Пантелеева ЕВ, Кощеев БВ, Maksimov AM, Рыбалова ТВ et al. Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. FLUORINE NOTES. 2019;123(2):7-8. doi: 10.17677/fn20714807.2019.02.04

Author

Fedyushin, Pavel A. ; Gurskaya, Larisa Yu ; Пантелеева, Елена Валерьевна et al. / Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. In: FLUORINE NOTES. 2019 ; Vol. 123, No. 2. pp. 7-8.

BibTeX

@article{b1d649d479184dea97ef1f2f3e898a4f,
title = "Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides",
abstract = "A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR",
author = "Fedyushin, {Pavel A.} and Gurskaya, {Larisa Yu} and Пантелеева, {Елена Валерьевна} and Кощеев, {Борислав Вячеславович} and Maksimov, {Alexander M.} and Рыбалова, {Татьяна Валерьевна} and Зайцева, {Елена Васильевна} and Третьяков, {Евгений Викторович}",
year = "2019",
doi = "10.17677/fn20714807.2019.02.04",
language = "English",
volume = "123",
pages = "7--8",
journal = "FLUORINE NOTES",
issn = "2071-4807",
number = "2",

}

RIS

TY - JOUR

T1 - Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides

AU - Fedyushin, Pavel A.

AU - Gurskaya, Larisa Yu

AU - Пантелеева, Елена Валерьевна

AU - Кощеев, Борислав Вячеславович

AU - Maksimov, Alexander M.

AU - Рыбалова, Татьяна Валерьевна

AU - Зайцева, Елена Васильевна

AU - Третьяков, Евгений Викторович

PY - 2019

Y1 - 2019

N2 - A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR

AB - A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR

U2 - 10.17677/fn20714807.2019.02.04

DO - 10.17677/fn20714807.2019.02.04

M3 - Article

VL - 123

SP - 7

EP - 8

JO - FLUORINE NOTES

JF - FLUORINE NOTES

SN - 2071-4807

IS - 2

ER -

ID: 22851117