Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. / Fedyushin, Pavel A.; Gurskaya, Larisa Yu; Пантелеева, Елена Валерьевна и др.
в: FLUORINE NOTES, Том 123, № 2, 2019, стр. 7-8.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides
AU - Fedyushin, Pavel A.
AU - Gurskaya, Larisa Yu
AU - Пантелеева, Елена Валерьевна
AU - Кощеев, Борислав Вячеславович
AU - Maksimov, Alexander M.
AU - Рыбалова, Татьяна Валерьевна
AU - Зайцева, Елена Васильевна
AU - Третьяков, Евгений Викторович
PY - 2019
Y1 - 2019
N2 - A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR
AB - A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR
U2 - 10.17677/fn20714807.2019.02.04
DO - 10.17677/fn20714807.2019.02.04
M3 - Article
VL - 123
SP - 7
EP - 8
JO - FLUORINE NOTES
JF - FLUORINE NOTES
SN - 2071-4807
IS - 2
ER -
ID: 22851117