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Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties. / Gayfulin, Yakov M.; Ryzhikov, Maxim R.; Samsonenko, Denis G. et al.

In: Polyhedron, Vol. 151, 01.09.2018, p. 426-432.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Ryzhikov, MR, Samsonenko, DG & Mironov, YV 2018, 'Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties', Polyhedron, vol. 151, pp. 426-432. https://doi.org/10.1016/j.poly.2018.05.061

APA

Gayfulin, Y. M., Ryzhikov, M. R., Samsonenko, D. G., & Mironov, Y. V. (2018). Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties. Polyhedron, 151, 426-432. https://doi.org/10.1016/j.poly.2018.05.061

Vancouver

Gayfulin YM, Ryzhikov MR, Samsonenko DG, Mironov YV. Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties. Polyhedron. 2018 Sept 1;151:426-432. doi: 10.1016/j.poly.2018.05.061

Author

Gayfulin, Yakov M. ; Ryzhikov, Maxim R. ; Samsonenko, Denis G. et al. / Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties. In: Polyhedron. 2018 ; Vol. 151. pp. 426-432.

BibTeX

@article{abe71127d9d44ae0bcf9075c5a19ff44,
title = "Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties",
abstract = "A first method for obtaining of electron-rich bioctahedral rhenium clusters has been developed. Two cluster salts, namely (Et3NH)4(Me2NH2)4[Re12CS14(µ-S)3Cl6] (1) and (Et4N)4(Me2NH2)4[Re12CS14(µ-S)3Br6] (2), have been synthesized and isolated in the solid state. Single-crystal X-ray diffraction showed that salts 1 and 2 are based on the new cluster anions [Re12CS14(µ-S)3Cl6]8− and [Re12CS14(µ-S)3Br6]8− containing 48 cluster valence electrons (CVE). The correlations between geometry and CVE number of the bioctahedral chalcohalide anions have been examined using the DFT calculations. The dissolution of the salts 1 and 2 is accompanied by the oxidation yielding the [Re12CS14(µ-S)3Cl6]6− and [Re12CS14(µ-S)3Br6]6− anions. Properties of the new clusters in the DMSO solutions have been investigated by UV–Vis spectroscopy and cyclic voltammetry. The latter revealed the presence of multiple reversible one-electron redox waves in a narrow potential window.",
keywords = "Cluster compound, Crystal structure, DFT calculations, Redox properties, Rhenium, POLYMERS, LIGANDS, MOLYBDENUM, COMPLEXES, METAL, FRAMEWORKS",
author = "Gayfulin, {Yakov M.} and Ryzhikov, {Maxim R.} and Samsonenko, {Denis G.} and Mironov, {Yuri V.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",
year = "2018",
month = sep,
day = "1",
doi = "10.1016/j.poly.2018.05.061",
language = "English",
volume = "151",
pages = "426--432",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Electron-rich bioctahedral rhenium chalcohalide clusters [Re12CS14(µ-S)3Cl6]8- and [Re12CS14(µ-S)3Br6]8-: Synthesis, structure and properties

AU - Gayfulin, Yakov M.

AU - Ryzhikov, Maxim R.

AU - Samsonenko, Denis G.

AU - Mironov, Yuri V.

N1 - Publisher Copyright: © 2018 Elsevier Ltd

PY - 2018/9/1

Y1 - 2018/9/1

N2 - A first method for obtaining of electron-rich bioctahedral rhenium clusters has been developed. Two cluster salts, namely (Et3NH)4(Me2NH2)4[Re12CS14(µ-S)3Cl6] (1) and (Et4N)4(Me2NH2)4[Re12CS14(µ-S)3Br6] (2), have been synthesized and isolated in the solid state. Single-crystal X-ray diffraction showed that salts 1 and 2 are based on the new cluster anions [Re12CS14(µ-S)3Cl6]8− and [Re12CS14(µ-S)3Br6]8− containing 48 cluster valence electrons (CVE). The correlations between geometry and CVE number of the bioctahedral chalcohalide anions have been examined using the DFT calculations. The dissolution of the salts 1 and 2 is accompanied by the oxidation yielding the [Re12CS14(µ-S)3Cl6]6− and [Re12CS14(µ-S)3Br6]6− anions. Properties of the new clusters in the DMSO solutions have been investigated by UV–Vis spectroscopy and cyclic voltammetry. The latter revealed the presence of multiple reversible one-electron redox waves in a narrow potential window.

AB - A first method for obtaining of electron-rich bioctahedral rhenium clusters has been developed. Two cluster salts, namely (Et3NH)4(Me2NH2)4[Re12CS14(µ-S)3Cl6] (1) and (Et4N)4(Me2NH2)4[Re12CS14(µ-S)3Br6] (2), have been synthesized and isolated in the solid state. Single-crystal X-ray diffraction showed that salts 1 and 2 are based on the new cluster anions [Re12CS14(µ-S)3Cl6]8− and [Re12CS14(µ-S)3Br6]8− containing 48 cluster valence electrons (CVE). The correlations between geometry and CVE number of the bioctahedral chalcohalide anions have been examined using the DFT calculations. The dissolution of the salts 1 and 2 is accompanied by the oxidation yielding the [Re12CS14(µ-S)3Cl6]6− and [Re12CS14(µ-S)3Br6]6− anions. Properties of the new clusters in the DMSO solutions have been investigated by UV–Vis spectroscopy and cyclic voltammetry. The latter revealed the presence of multiple reversible one-electron redox waves in a narrow potential window.

KW - Cluster compound

KW - Crystal structure

KW - DFT calculations

KW - Redox properties

KW - Rhenium

KW - POLYMERS

KW - LIGANDS

KW - MOLYBDENUM

KW - COMPLEXES

KW - METAL

KW - FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85048784870&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2018.05.061

DO - 10.1016/j.poly.2018.05.061

M3 - Article

AN - SCOPUS:85048784870

VL - 151

SP - 426

EP - 432

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 14101547