Research output: Contribution to journal › Article › peer-review
Electron transport properties of thermoelectrics based on layered substituted transition metal dichalcogenides. / Romanenko, A. I.; Yakovleva, G. E.; Fedorov, V. E. et al.
In: Journal of Structural Chemistry, Vol. 58, No. 5, 01.09.2017, p. 893-900.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electron transport properties of thermoelectrics based on layered substituted transition metal dichalcogenides
AU - Romanenko, A. I.
AU - Yakovleva, G. E.
AU - Fedorov, V. E.
AU - Ledneva, A. Yu
AU - Kuznetsov, V. A.
AU - Sotnikov, A. V.
AU - Tsygankova, A. R.
AU - Kuchumov, B. M.
N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.
PY - 2017/9/1
Y1 - 2017/9/1
N2 - Temperature dependences of the electrical conductivity are studied in the range 4.2’300 K and Seebeck coefficient at room temperature of bulk samples of tungsten dichalcogenide polycrystals with niobium substitutions for tungsten and selenium substitutions for sulfur – W1–xNbx(S1–ySey)2. The two-dimensionalization of electron transport properties is detected at niobium concentrations x ≥ 0.1 in W1–xNbxS2 and x ≥ 0.05 in W1–xNbxSe2. In samples with additional partial selenium substitution for sulfur the electron transport remains three-dimensional. At room temperature the Seebeck coefficient (at equal electrical conductivities) is several times higher in the samples with quasi-two-dimensional transport than in the samples with three-dimensional transport. The calculation of the power factor at room temperature shows its nine times increase.
AB - Temperature dependences of the electrical conductivity are studied in the range 4.2’300 K and Seebeck coefficient at room temperature of bulk samples of tungsten dichalcogenide polycrystals with niobium substitutions for tungsten and selenium substitutions for sulfur – W1–xNbx(S1–ySey)2. The two-dimensionalization of electron transport properties is detected at niobium concentrations x ≥ 0.1 in W1–xNbxS2 and x ≥ 0.05 in W1–xNbxSe2. In samples with additional partial selenium substitution for sulfur the electron transport remains three-dimensional. At room temperature the Seebeck coefficient (at equal electrical conductivities) is several times higher in the samples with quasi-two-dimensional transport than in the samples with three-dimensional transport. The calculation of the power factor at room temperature shows its nine times increase.
KW - electrical conductivity
KW - layered transition metal chalcogenides
KW - Seebeck coefficient
KW - FIGURE
UR - http://www.scopus.com/inward/record.url?scp=85032001093&partnerID=8YFLogxK
U2 - 10.1134/S0022476617050067
DO - 10.1134/S0022476617050067
M3 - Article
AN - SCOPUS:85032001093
VL - 58
SP - 893
EP - 900
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 5
ER -
ID: 9874524