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Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation. / Sigaeva, S. S.; Afonasenkova, T. N.; Bulavchenko, O. A. et al.

In: Russian Journal of Applied Chemistry, Vol. 90, No. 12, 01.12.2017, p. 1918-1925.

Research output: Contribution to journal › Article › peer-review

Harvard

Sigaeva, SS, Afonasenkova, TN, Bulavchenko, OA, Gulyaeva, TI, Anoshkina, EA & Tsyrul’nikov, PG 2017, 'Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation', Russian Journal of Applied Chemistry, vol. 90, no. 12, pp. 1918-1925. https://doi.org/10.1134/S1070427217120047

APA

Sigaeva, S. S., Afonasenkova, T. N., Bulavchenko, O. A., Gulyaeva, T. I., Anoshkina, E. A., & Tsyrul’nikov, P. G. (2017). Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation. Russian Journal of Applied Chemistry, 90(12), 1918-1925. https://doi.org/10.1134/S1070427217120047

Vancouver

Sigaeva SS, Afonasenkova TN, Bulavchenko OA, Gulyaeva TI, Anoshkina EA, Tsyrul’nikov PG. Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation. Russian Journal of Applied Chemistry. 2017 Dec 1;90(12):1918-1925. doi: 10.1134/S1070427217120047

Author

Sigaeva, S. S. ; Afonasenkova, T. N. ; Bulavchenko, O. A. et al. / Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation. In: Russian Journal of Applied Chemistry. 2017 ; Vol. 90, No. 12. pp. 1918-1925.

BibTeX

@article{5470910e5d34476aa66897991b54ece2,
title = "Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation",
abstract = "Effect of the calcination temperature of the MnOx/Ga2O3 system on its structural and catalytic properties in the reaction of oxidation of CO and hydrocarbons. The dependences of the catalytic activity of MnOx/Ga2O3 in the reactions of CO and ethane oxidation on the calcination temperature exhibit an extremal behavior. The maximum values of activity are observed upon calcination of the system at 700°C, i.e., at the temperature that is limiting for the existence of a solid solution of manganese ions in γ-Ga2O3. The structural changes occurring with increasing calcination temperature are accompanied by a substantial decrease in the specific surface area of a sample. The observed rise in the specific catalytic activity (by a factor of ~7 upon an increase in the preliminary-calcination temperature from 600 to 800°C) confirms that the thermal activation effect exists for the given system.",
keywords = "MANGANESE, MN1.5AL1.5O4, ACTIVATION, SPINEL",
author = "Sigaeva, {S. S.} and Afonasenkova, {T. N.} and Bulavchenko, {O. A.} and Gulyaeva, {T. I.} and Anoshkina, {E. A.} and Tsyrul{\textquoteright}nikov, {P. G.}",
year = "2017",
month = dec,
day = "1",
doi = "10.1134/S1070427217120047",
language = "English",
volume = "90",
pages = "1918--1925",
journal = "Russian Journal of Applied Chemistry",
issn = "1070-4272",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "12",

}

RIS

TY - JOUR

T1 - Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation

AU - Sigaeva, S. S.

AU - Afonasenkova, T. N.

AU - Bulavchenko, O. A.

AU - Gulyaeva, T. I.

AU - Anoshkina, E. A.

AU - Tsyrul’nikov, P. G.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Effect of the calcination temperature of the MnOx/Ga2O3 system on its structural and catalytic properties in the reaction of oxidation of CO and hydrocarbons. The dependences of the catalytic activity of MnOx/Ga2O3 in the reactions of CO and ethane oxidation on the calcination temperature exhibit an extremal behavior. The maximum values of activity are observed upon calcination of the system at 700°C, i.e., at the temperature that is limiting for the existence of a solid solution of manganese ions in γ-Ga2O3. The structural changes occurring with increasing calcination temperature are accompanied by a substantial decrease in the specific surface area of a sample. The observed rise in the specific catalytic activity (by a factor of ~7 upon an increase in the preliminary-calcination temperature from 600 to 800°C) confirms that the thermal activation effect exists for the given system.

AB - Effect of the calcination temperature of the MnOx/Ga2O3 system on its structural and catalytic properties in the reaction of oxidation of CO and hydrocarbons. The dependences of the catalytic activity of MnOx/Ga2O3 in the reactions of CO and ethane oxidation on the calcination temperature exhibit an extremal behavior. The maximum values of activity are observed upon calcination of the system at 700°C, i.e., at the temperature that is limiting for the existence of a solid solution of manganese ions in γ-Ga2O3. The structural changes occurring with increasing calcination temperature are accompanied by a substantial decrease in the specific surface area of a sample. The observed rise in the specific catalytic activity (by a factor of ~7 upon an increase in the preliminary-calcination temperature from 600 to 800°C) confirms that the thermal activation effect exists for the given system.

KW - MANGANESE

KW - MN1.5AL1.5O4

KW - ACTIVATION

KW - SPINEL

UR - http://www.scopus.com/inward/record.url?scp=85045238086&partnerID=8YFLogxK

U2 - 10.1134/S1070427217120047

DO - 10.1134/S1070427217120047

M3 - Article

AN - SCOPUS:85045238086

VL - 90

SP - 1918

EP - 1925

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

SN - 1070-4272

IS - 12

ER -

ID: 12631458