Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation. / Sigaeva, S. S.; Afonasenkova, T. N.; Bulavchenko, O. A. и др.
в: Russian Journal of Applied Chemistry, Том 90, № 12, 01.12.2017, стр. 1918-1925.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Effect of Calcination Temperature on the Structure and Catalytic Properties of MnOx/Ca2O3 in the Reaction of CO and Ethane Oxidation
AU - Sigaeva, S. S.
AU - Afonasenkova, T. N.
AU - Bulavchenko, O. A.
AU - Gulyaeva, T. I.
AU - Anoshkina, E. A.
AU - Tsyrul’nikov, P. G.
PY - 2017/12/1
Y1 - 2017/12/1
N2 - Effect of the calcination temperature of the MnOx/Ga2O3 system on its structural and catalytic properties in the reaction of oxidation of CO and hydrocarbons. The dependences of the catalytic activity of MnOx/Ga2O3 in the reactions of CO and ethane oxidation on the calcination temperature exhibit an extremal behavior. The maximum values of activity are observed upon calcination of the system at 700°C, i.e., at the temperature that is limiting for the existence of a solid solution of manganese ions in γ-Ga2O3. The structural changes occurring with increasing calcination temperature are accompanied by a substantial decrease in the specific surface area of a sample. The observed rise in the specific catalytic activity (by a factor of ~7 upon an increase in the preliminary-calcination temperature from 600 to 800°C) confirms that the thermal activation effect exists for the given system.
AB - Effect of the calcination temperature of the MnOx/Ga2O3 system on its structural and catalytic properties in the reaction of oxidation of CO and hydrocarbons. The dependences of the catalytic activity of MnOx/Ga2O3 in the reactions of CO and ethane oxidation on the calcination temperature exhibit an extremal behavior. The maximum values of activity are observed upon calcination of the system at 700°C, i.e., at the temperature that is limiting for the existence of a solid solution of manganese ions in γ-Ga2O3. The structural changes occurring with increasing calcination temperature are accompanied by a substantial decrease in the specific surface area of a sample. The observed rise in the specific catalytic activity (by a factor of ~7 upon an increase in the preliminary-calcination temperature from 600 to 800°C) confirms that the thermal activation effect exists for the given system.
KW - MANGANESE
KW - MN1.5AL1.5O4
KW - ACTIVATION
KW - SPINEL
UR - http://www.scopus.com/inward/record.url?scp=85045238086&partnerID=8YFLogxK
U2 - 10.1134/S1070427217120047
DO - 10.1134/S1070427217120047
M3 - Article
AN - SCOPUS:85045238086
VL - 90
SP - 1918
EP - 1925
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
SN - 1070-4272
IS - 12
ER -
ID: 12631458