Different reductive reactivities of SmCpx 2(THF)n (Cpx = C5Me5 and C5H3 tBu2) samarocenes toward P2Ph4

RAY CRYSTAL-STRUCTURE, DIVALENT LANTHANIDE CHEMISTRY, RARE-EARTH-ELEMENTS, ELECTRON-DENSITY, STRUCTURAL-CHARACTERIZATION, MOLECULAR-COMPLEXES, SUPERBULKY LIGANDS, OXIDATION-STATE, BOND FORMATION, BASIS-SETS

ID: 10191226

Different reductive reactivities of SmCpx 2(THF)n (Cpx = C5Me5 and C5H3 tBu2) samarocenes toward P2Ph4: THF ring-opening and ligand-exchange pathways