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Deprotonation of Benzoxazolium Salt : Trapping of a Radical-Cation Intermediate. / Klementyeva, Svetlana V.; Abramov, Pavel A.; Somov, Nikolay V. et al.

In: Organic Letters, Vol. 21, No. 4, 15.02.2019, p. 946-950.

Research output: Contribution to journal › Article › peer-review

Harvard

Klementyeva, SV, Abramov, PA, Somov, NV, Dudkina, YB, Budnikova, YH & Poddel'Sky, AI 2019, 'Deprotonation of Benzoxazolium Salt: Trapping of a Radical-Cation Intermediate', Organic Letters, vol. 21, no. 4, pp. 946-950. https://doi.org/10.1021/acs.orglett.8b03928

APA

Klementyeva, S. V., Abramov, P. A., Somov, N. V., Dudkina, Y. B., Budnikova, Y. H., & Poddel'Sky, A. I. (2019). Deprotonation of Benzoxazolium Salt: Trapping of a Radical-Cation Intermediate. Organic Letters, 21(4), 946-950. https://doi.org/10.1021/acs.orglett.8b03928

Vancouver

Klementyeva SV, Abramov PA, Somov NV, Dudkina YB, Budnikova YH, Poddel'Sky AI. Deprotonation of Benzoxazolium Salt: Trapping of a Radical-Cation Intermediate. Organic Letters. 2019 Feb 15;21(4):946-950. doi: 10.1021/acs.orglett.8b03928

Author

Klementyeva, Svetlana V. ; Abramov, Pavel A. ; Somov, Nikolay V. et al. / Deprotonation of Benzoxazolium Salt : Trapping of a Radical-Cation Intermediate. In: Organic Letters. 2019 ; Vol. 21, No. 4. pp. 946-950.

BibTeX

@article{31b2d2e50cb6423985a7759980bef9e0,
title = "Deprotonation of Benzoxazolium Salt: Trapping of a Radical-Cation Intermediate",
abstract = " The deprotonation of N-2,6-diisopropylphenyl-substituted benzoxazolium tetrafluoroborate 1 with NaH results in the formation of electron-rich diaminodioxaethylene 2. The radical cation salt 2 ·+ ·BF 4 - is found to be an intermediate product in the redox reaction leading from 1 to 2. ",
keywords = "N-HETEROCYCLIC CARBENES, TRANSITION-METAL-COMPLEXES, COORDINATION CHEMISTRY, IMIDAZOLIUM SALTS, LIGANDS, REACTIVITY, PRECURSORS, ISOCYANIDE, OXIDATION, CATALYSTS",
author = "Klementyeva, {Svetlana V.} and Abramov, {Pavel A.} and Somov, {Nikolay V.} and Dudkina, {Yulia B.} and Budnikova, {Yulia H.} and Poddel'Sky, {Andrey I.}",
note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",
year = "2019",
month = feb,
day = "15",
doi = "10.1021/acs.orglett.8b03928",
language = "English",
volume = "21",
pages = "946--950",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Deprotonation of Benzoxazolium Salt

T2 - Trapping of a Radical-Cation Intermediate

AU - Klementyeva, Svetlana V.

AU - Abramov, Pavel A.

AU - Somov, Nikolay V.

AU - Dudkina, Yulia B.

AU - Budnikova, Yulia H.

AU - Poddel'Sky, Andrey I.

N1 - Publisher Copyright: Copyright © 2019 American Chemical Society.

PY - 2019/2/15

Y1 - 2019/2/15

N2 - The deprotonation of N-2,6-diisopropylphenyl-substituted benzoxazolium tetrafluoroborate 1 with NaH results in the formation of electron-rich diaminodioxaethylene 2. The radical cation salt 2 ·+ ·BF 4 - is found to be an intermediate product in the redox reaction leading from 1 to 2.

AB - The deprotonation of N-2,6-diisopropylphenyl-substituted benzoxazolium tetrafluoroborate 1 with NaH results in the formation of electron-rich diaminodioxaethylene 2. The radical cation salt 2 ·+ ·BF 4 - is found to be an intermediate product in the redox reaction leading from 1 to 2.

KW - N-HETEROCYCLIC CARBENES

KW - TRANSITION-METAL-COMPLEXES

KW - COORDINATION CHEMISTRY

KW - IMIDAZOLIUM SALTS

KW - LIGANDS

KW - REACTIVITY

KW - PRECURSORS

KW - ISOCYANIDE

KW - OXIDATION

KW - CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85061276130&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.8b03928

DO - 10.1021/acs.orglett.8b03928

M3 - Article

C2 - 30698444

AN - SCOPUS:85061276130

VL - 21

SP - 946

EP - 950

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 4

ER -

ID: 18485417