Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Deprotonation of Benzoxazolium Salt : Trapping of a Radical-Cation Intermediate. / Klementyeva, Svetlana V.; Abramov, Pavel A.; Somov, Nikolay V. и др.
в: Organic Letters, Том 21, № 4, 15.02.2019, стр. 946-950.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Deprotonation of Benzoxazolium Salt
T2 - Trapping of a Radical-Cation Intermediate
AU - Klementyeva, Svetlana V.
AU - Abramov, Pavel A.
AU - Somov, Nikolay V.
AU - Dudkina, Yulia B.
AU - Budnikova, Yulia H.
AU - Poddel'Sky, Andrey I.
N1 - Publisher Copyright: Copyright © 2019 American Chemical Society.
PY - 2019/2/15
Y1 - 2019/2/15
N2 - The deprotonation of N-2,6-diisopropylphenyl-substituted benzoxazolium tetrafluoroborate 1 with NaH results in the formation of electron-rich diaminodioxaethylene 2. The radical cation salt 2 ·+ ·BF 4 - is found to be an intermediate product in the redox reaction leading from 1 to 2.
AB - The deprotonation of N-2,6-diisopropylphenyl-substituted benzoxazolium tetrafluoroborate 1 with NaH results in the formation of electron-rich diaminodioxaethylene 2. The radical cation salt 2 ·+ ·BF 4 - is found to be an intermediate product in the redox reaction leading from 1 to 2.
KW - N-HETEROCYCLIC CARBENES
KW - TRANSITION-METAL-COMPLEXES
KW - COORDINATION CHEMISTRY
KW - IMIDAZOLIUM SALTS
KW - LIGANDS
KW - REACTIVITY
KW - PRECURSORS
KW - ISOCYANIDE
KW - OXIDATION
KW - CATALYSTS
UR - http://www.scopus.com/inward/record.url?scp=85061276130&partnerID=8YFLogxK
U2 - 10.1021/acs.orglett.8b03928
DO - 10.1021/acs.orglett.8b03928
M3 - Article
C2 - 30698444
AN - SCOPUS:85061276130
VL - 21
SP - 946
EP - 950
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 4
ER -
ID: 18485417