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[Cu4I7 3−]n : A novel 1-D iodocuprate aggregate. / Artem'ev, Alexander V.; Bagryanskaya, Irina Yu.

In: Journal of Molecular Structure, Vol. 1173, 05.12.2018, p. 743-749.

Research output: Contribution to journal › Article › peer-review

Harvard

Artem'ev, AV & Bagryanskaya, IY 2018, '[Cu4I7 3−]n: A novel 1-D iodocuprate aggregate', Journal of Molecular Structure, vol. 1173, pp. 743-749. https://doi.org/10.1016/j.molstruc.2018.07.006

APA

Artem'ev, A. V., & Bagryanskaya, I. Y. (2018). [Cu4I7 3−]n: A novel 1-D iodocuprate aggregate. Journal of Molecular Structure, 1173, 743-749. https://doi.org/10.1016/j.molstruc.2018.07.006

Vancouver

Artem'ev AV, Bagryanskaya IY. [Cu4I7 3−]n: A novel 1-D iodocuprate aggregate. Journal of Molecular Structure. 2018 Dec 5;1173:743-749. doi: 10.1016/j.molstruc.2018.07.006

Author

Artem'ev, Alexander V. ; Bagryanskaya, Irina Yu. / [Cu4I7 3−]n : A novel 1-D iodocuprate aggregate. In: Journal of Molecular Structure. 2018 ; Vol. 1173. pp. 743-749.

BibTeX

@article{da190691195e477f8a46c21ac4173fdc,
title = "[Cu4I7 3−]n: A novel 1-D iodocuprate aggregate",
abstract = "A new cationic ligand, 1-methyl-3-(methylthio)pyrazin-1-ium iodide (MMTPI), has been designed and synthesized by regioselective alkylation of 2-methylthiopyrazine with MeI. Reaction of this ligand with CuI in a 3:4 molar ratio under mild conditions (MeCN, r.t.) produces new iodocuprate, [Cu4I7(MMTP)3]n, containing one-dimensional inorganic chains [Cu4I7 3−]n. The latter are constructed from the basket-shaped {[Cu3(μ3-I)](I)3(μ2-I)3} building blocks, which are linked by tetrahedral Cu atoms through bridging iodine atoms. The UV–Vis diffuse reflectance measurements reveal that the title iodocuprate possesses semiconductor behaviour with the band gap of 1.80 eV. The thermal stability and electronic structure of the iodocuprate are also discussed.",
keywords = "Coordination polymers, copper(I) complexes, Crystal structure, Iodocuprates, Pyrazines, Sulfide ligands, HALIDES, COMPLEXES, PHOTOCATALYSIS, CRYSTAL-STRUCTURES, CHEMISTRY, SYSTEMS, HYBRIDS",
author = "Artem'ev, {Alexander V.} and Bagryanskaya, {Irina Yu}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = dec,
day = "5",
doi = "10.1016/j.molstruc.2018.07.006",
language = "English",
volume = "1173",
pages = "743--749",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - [Cu4I7 3−]n

T2 - A novel 1-D iodocuprate aggregate

AU - Artem'ev, Alexander V.

AU - Bagryanskaya, Irina Yu

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/12/5

Y1 - 2018/12/5

N2 - A new cationic ligand, 1-methyl-3-(methylthio)pyrazin-1-ium iodide (MMTPI), has been designed and synthesized by regioselective alkylation of 2-methylthiopyrazine with MeI. Reaction of this ligand with CuI in a 3:4 molar ratio under mild conditions (MeCN, r.t.) produces new iodocuprate, [Cu4I7(MMTP)3]n, containing one-dimensional inorganic chains [Cu4I7 3−]n. The latter are constructed from the basket-shaped {[Cu3(μ3-I)](I)3(μ2-I)3} building blocks, which are linked by tetrahedral Cu atoms through bridging iodine atoms. The UV–Vis diffuse reflectance measurements reveal that the title iodocuprate possesses semiconductor behaviour with the band gap of 1.80 eV. The thermal stability and electronic structure of the iodocuprate are also discussed.

AB - A new cationic ligand, 1-methyl-3-(methylthio)pyrazin-1-ium iodide (MMTPI), has been designed and synthesized by regioselective alkylation of 2-methylthiopyrazine with MeI. Reaction of this ligand with CuI in a 3:4 molar ratio under mild conditions (MeCN, r.t.) produces new iodocuprate, [Cu4I7(MMTP)3]n, containing one-dimensional inorganic chains [Cu4I7 3−]n. The latter are constructed from the basket-shaped {[Cu3(μ3-I)](I)3(μ2-I)3} building blocks, which are linked by tetrahedral Cu atoms through bridging iodine atoms. The UV–Vis diffuse reflectance measurements reveal that the title iodocuprate possesses semiconductor behaviour with the band gap of 1.80 eV. The thermal stability and electronic structure of the iodocuprate are also discussed.

KW - Coordination polymers

KW - copper(I) complexes

KW - Crystal structure

KW - Iodocuprates

KW - Pyrazines

KW - Sulfide ligands

KW - HALIDES

KW - COMPLEXES

KW - PHOTOCATALYSIS

KW - CRYSTAL-STRUCTURES

KW - CHEMISTRY

KW - SYSTEMS

KW - HYBRIDS

UR - http://www.scopus.com/inward/record.url?scp=85050120667&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2018.07.006

DO - 10.1016/j.molstruc.2018.07.006

M3 - Article

AN - SCOPUS:85050120667

VL - 1173

SP - 743

EP - 749

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 15962838