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Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes. / Petrov, P. A.; Sukhikh, T. S.

In: Journal of Structural Chemistry, Vol. 59, No. 6, 01.11.2018, p. 1405-1411.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA & Sukhikh, TS 2018, 'Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes', Journal of Structural Chemistry, vol. 59, no. 6, pp. 1405-1411. https://doi.org/10.1134/S0022476618060227

APA

Petrov, P. A., & Sukhikh, T. S. (2018). Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes. Journal of Structural Chemistry, 59(6), 1405-1411. https://doi.org/10.1134/S0022476618060227

Vancouver

Petrov PA, Sukhikh TS. Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes. Journal of Structural Chemistry. 2018 Nov 1;59(6):1405-1411. doi: 10.1134/S0022476618060227

Author

Petrov, P. A. ; Sukhikh, T. S. / Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 6. pp. 1405-1411.

BibTeX

@article{15651a7711cd4f06bbe396fda1fd7845,
title = "Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes",
abstract = "In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.",
keywords = "chromium, decamethylchromocene, quinones, single crystal XRD, SALT, REDUCTION, LIGANDS, ORGANOMETALLIC OXIDES, OXIDATION-STATES, MAGNETIC-PROPERTIES",
author = "Petrov, {P. A.} and Sukhikh, {T. S.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = nov,
day = "1",
doi = "10.1134/S0022476618060227",
language = "English",
volume = "59",
pages = "1405--1411",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

AU - Petrov, P. A.

AU - Sukhikh, T. S.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

AB - In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

KW - chromium

KW - decamethylchromocene

KW - quinones

KW - single crystal XRD

KW - SALT

KW - REDUCTION

KW - LIGANDS

KW - ORGANOMETALLIC OXIDES

KW - OXIDATION-STATES

KW - MAGNETIC-PROPERTIES

UR - http://www.scopus.com/inward/record.url?scp=85058464326&partnerID=8YFLogxK

U2 - 10.1134/S0022476618060227

DO - 10.1134/S0022476618060227

M3 - Article

AN - SCOPUS:85058464326

VL - 59

SP - 1405

EP - 1411

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 17879492