Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes. / Petrov, P. A.; Sukhikh, T. S.
в: Journal of Structural Chemistry, Том 59, № 6, 01.11.2018, стр. 1405-1411.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes
AU - Petrov, P. A.
AU - Sukhikh, T. S.
N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.
AB - In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.
KW - chromium
KW - decamethylchromocene
KW - quinones
KW - single crystal XRD
KW - SALT
KW - REDUCTION
KW - LIGANDS
KW - ORGANOMETALLIC OXIDES
KW - OXIDATION-STATES
KW - MAGNETIC-PROPERTIES
UR - http://www.scopus.com/inward/record.url?scp=85058464326&partnerID=8YFLogxK
U2 - 10.1134/S0022476618060227
DO - 10.1134/S0022476618060227
M3 - Article
AN - SCOPUS:85058464326
VL - 59
SP - 1405
EP - 1411
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 6
ER -
ID: 17879492