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Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]. / Gayfulin, Ya M.; Smolentsev, A. I.; Mironov, Yu V. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 1, 01.01.2017, p. 203-206.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Smolentsev, AI, Mironov, YV & Naumov, NG 2017, 'Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]', Journal of Structural Chemistry, vol. 58, no. 1, pp. 203-206. https://doi.org/10.1134/S0022476617010292

APA

Gayfulin, Y. M., Smolentsev, A. I., Mironov, Y. V., & Naumov, N. G. (2017). Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]. Journal of Structural Chemistry, 58(1), 203-206. https://doi.org/10.1134/S0022476617010292

Vancouver

Gayfulin YM, Smolentsev AI, Mironov YV, Naumov NG. Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]. Journal of Structural Chemistry. 2017 Jan 1;58(1):203-206. doi: 10.1134/S0022476617010292

Author

Gayfulin, Ya M. ; Smolentsev, A. I. ; Mironov, Yu V. et al. / Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 1. pp. 203-206.

BibTeX

@article{fef492643ac44ccf93199de382d80a5d,
title = "Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]",
abstract = "Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.",
keywords = "crystal structure, heterometallic cluster complex, molybdenum, polymer, rhenium, synthesis",
author = "Gayfulin, {Ya M.} and Smolentsev, {A. I.} and Mironov, {Yu V.} and Naumov, {N. G.}",
year = "2017",
month = jan,
day = "1",
doi = "10.1134/S0022476617010292",
language = "English",
volume = "58",
pages = "203--206",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]

AU - Gayfulin, Ya M.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

AU - Naumov, N. G.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.

AB - Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.

KW - crystal structure

KW - heterometallic cluster complex

KW - molybdenum

KW - polymer

KW - rhenium

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85016016035&partnerID=8YFLogxK

U2 - 10.1134/S0022476617010292

DO - 10.1134/S0022476617010292

M3 - Article

AN - SCOPUS:85016016035

VL - 58

SP - 203

EP - 206

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 10270920