Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]. / Gayfulin, Ya M.; Smolentsev, A. I.; Mironov, Yu V. и др.
в: Journal of Structural Chemistry, Том 58, № 1, 01.01.2017, стр. 203-206.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]
AU - Gayfulin, Ya M.
AU - Smolentsev, A. I.
AU - Mironov, Yu V.
AU - Naumov, N. G.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.
AB - Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.
KW - crystal structure
KW - heterometallic cluster complex
KW - molybdenum
KW - polymer
KW - rhenium
KW - synthesis
UR - http://www.scopus.com/inward/record.url?scp=85016016035&partnerID=8YFLogxK
U2 - 10.1134/S0022476617010292
DO - 10.1134/S0022476617010292
M3 - Article
AN - SCOPUS:85016016035
VL - 58
SP - 203
EP - 206
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 1
ER -
ID: 10270920