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Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex. / Ivanov, A. A.; Kuratieva, N. V.; Shestopalov, M. A. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 5, 01.09.2017, p. 989-993.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanov, AA, Kuratieva, NV, Shestopalov, MA & Mironov, YV 2017, 'Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex', Journal of Structural Chemistry, vol. 58, no. 5, pp. 989-993. https://doi.org/10.1134/S0022476617050195

APA

Ivanov, A. A., Kuratieva, N. V., Shestopalov, M. A., & Mironov, Y. V. (2017). Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex. Journal of Structural Chemistry, 58(5), 989-993. https://doi.org/10.1134/S0022476617050195

Vancouver

Ivanov AA, Kuratieva NV, Shestopalov MA, Mironov YV. Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex. Journal of Structural Chemistry. 2017 Sept 1;58(5):989-993. doi: 10.1134/S0022476617050195

Author

Ivanov, A. A. ; Kuratieva, N. V. ; Shestopalov, M. A. et al. / Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 5. pp. 989-993.

BibTeX

@article{f81e78feb5c74ed58c8836026f94d59a,
title = "Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex",
abstract = "A cluster complex of the composition [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] is obtained by the reaction of K4[{Re6(μ3-Se)8}(OH)6]·8H2O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) {\AA}, b = 14.7584(4) {\AA}, c = 18.1573(4) {\AA}, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) {\AA}3, Z = 2, dcalc = 3.130 g/cm3. The crystal structure is built of [{Re6Se8}Br6]3– anionic cluster complexes and complex [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4]3+ cations.",
keywords = "crystal structure, octahedral chalcogenide clusters, rhenium, CORE, ORGANIC-LIGANDS, ENCAPSULATION, LUMINESCENCE PROPERTIES, RHENIUM, CHALCOGENIDE CLUSTERS, SE, OCTAHEDRAL CLUSTERS, SILICA NANOPARTICLES, CHEMISTRY",
author = "Ivanov, {A. A.} and Kuratieva, {N. V.} and Shestopalov, {M. A.} and Mironov, {Yu V.}",
year = "2017",
month = sep,
day = "1",
doi = "10.1134/S0022476617050195",
language = "English",
volume = "58",
pages = "989--993",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex

AU - Ivanov, A. A.

AU - Kuratieva, N. V.

AU - Shestopalov, M. A.

AU - Mironov, Yu V.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - A cluster complex of the composition [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] is obtained by the reaction of K4[{Re6(μ3-Se)8}(OH)6]·8H2O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) Å, b = 14.7584(4) Å, c = 18.1573(4) Å, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) Å3, Z = 2, dcalc = 3.130 g/cm3. The crystal structure is built of [{Re6Se8}Br6]3– anionic cluster complexes and complex [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4]3+ cations.

AB - A cluster complex of the composition [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] is obtained by the reaction of K4[{Re6(μ3-Se)8}(OH)6]·8H2O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) Å, b = 14.7584(4) Å, c = 18.1573(4) Å, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) Å3, Z = 2, dcalc = 3.130 g/cm3. The crystal structure is built of [{Re6Se8}Br6]3– anionic cluster complexes and complex [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4]3+ cations.

KW - crystal structure

KW - octahedral chalcogenide clusters

KW - rhenium

KW - CORE

KW - ORGANIC-LIGANDS

KW - ENCAPSULATION

KW - LUMINESCENCE PROPERTIES

KW - RHENIUM

KW - CHALCOGENIDE CLUSTERS

KW - SE

KW - OCTAHEDRAL CLUSTERS

KW - SILICA NANOPARTICLES

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=85032288600&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050195

DO - 10.1134/S0022476617050195

M3 - Article

AN - SCOPUS:85032288600

VL - 58

SP - 989

EP - 993

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 9873573