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Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3. / Moshkina, Evgeniya; Seryotkin, Yurii; Bovina, Asya et al.

In: Journal of Crystal Growth, Vol. 503, 01.12.2018, p. 1-8.

Research output: Contribution to journal › Article › peer-review

Harvard

Moshkina, E, Seryotkin, Y, Bovina, A, Molokeev, M, Eremin, E, Belskaya, N & Bezmaternykh, L 2018, 'Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3', Journal of Crystal Growth, vol. 503, pp. 1-8. https://doi.org/10.1016/j.jcrysgro.2018.09.011

APA

Moshkina, E., Seryotkin, Y., Bovina, A., Molokeev, M., Eremin, E., Belskaya, N., & Bezmaternykh, L. (2018). Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3. Journal of Crystal Growth, 503, 1-8. https://doi.org/10.1016/j.jcrysgro.2018.09.011

Vancouver

Moshkina E, Seryotkin Y, Bovina A, Molokeev M, Eremin E, Belskaya N et al. Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3. Journal of Crystal Growth. 2018 Dec 1;503:1-8. doi: 10.1016/j.jcrysgro.2018.09.011

Author

Moshkina, Evgeniya ; Seryotkin, Yurii ; Bovina, Asya et al. / Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3. In: Journal of Crystal Growth. 2018 ; Vol. 503. pp. 1-8.

BibTeX

@article{037bcb4dd42c434780d2e440767c37b3,
title = "Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3",
abstract = "The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 ≤ Mn2O3:CuO ≤ 5) are studied. The conditions of the stable crystallization of Mn2+ 1−xCuxMoO4, Mn2 3+O3, Mn2+Mn2 3+O4, Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+- and Mn3+-containing Mn2+ 1−xCuxMoO4 and Mn2+Mn2 3+O4 and Mn2 3+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented.",
keywords = "A1.Characterization, A2.Growth from solutions, A2.Single crystal growth, B1.Manganites, B2.Magnetic materials, Growth from solutions, Single crystal growth, Characterization, MAGNETISM, SINGLE-CRYSTALS, GROWTH, LUDWIGITE, Magnetic materials, Manganites",
author = "Evgeniya Moshkina and Yurii Seryotkin and Asya Bovina and Maxim Molokeev and Evgeniy Eremin and Nadejda Belskaya and Leonard Bezmaternykh",
year = "2018",
month = dec,
day = "1",
doi = "10.1016/j.jcrysgro.2018.09.011",
language = "English",
volume = "503",
pages = "1--8",
journal = "Journal of Crystal Growth",
issn = "0022-0248",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3

AU - Moshkina, Evgeniya

AU - Seryotkin, Yurii

AU - Bovina, Asya

AU - Molokeev, Maxim

AU - Eremin, Evgeniy

AU - Belskaya, Nadejda

AU - Bezmaternykh, Leonard

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 ≤ Mn2O3:CuO ≤ 5) are studied. The conditions of the stable crystallization of Mn2+ 1−xCuxMoO4, Mn2 3+O3, Mn2+Mn2 3+O4, Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+- and Mn3+-containing Mn2+ 1−xCuxMoO4 and Mn2+Mn2 3+O4 and Mn2 3+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented.

AB - The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 ≤ Mn2O3:CuO ≤ 5) are studied. The conditions of the stable crystallization of Mn2+ 1−xCuxMoO4, Mn2 3+O3, Mn2+Mn2 3+O4, Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+- and Mn3+-containing Mn2+ 1−xCuxMoO4 and Mn2+Mn2 3+O4 and Mn2 3+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented.

KW - A1.Characterization

KW - A2.Growth from solutions

KW - A2.Single crystal growth

KW - B1.Manganites

KW - B2.Magnetic materials

KW - Growth from solutions

KW - Single crystal growth

KW - Characterization

KW - MAGNETISM

KW - SINGLE-CRYSTALS

KW - GROWTH

KW - LUDWIGITE

KW - Magnetic materials

KW - Manganites

UR - http://www.scopus.com/inward/record.url?scp=85053797039&partnerID=8YFLogxK

U2 - 10.1016/j.jcrysgro.2018.09.011

DO - 10.1016/j.jcrysgro.2018.09.011

M3 - Article

AN - SCOPUS:85053797039

VL - 503

SP - 1

EP - 8

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

SN - 0022-0248

ER -

ID: 16703698