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Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3. / Moshkina, Evgeniya; Seryotkin, Yurii; Bovina, Asya и др.
в: Journal of Crystal Growth, Том 503, 01.12.2018, стр. 1-8.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3
AU - Moshkina, Evgeniya
AU - Seryotkin, Yurii
AU - Bovina, Asya
AU - Molokeev, Maxim
AU - Eremin, Evgeniy
AU - Belskaya, Nadejda
AU - Bezmaternykh, Leonard
PY - 2018/12/1
Y1 - 2018/12/1
N2 - The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 ≤ Mn2O3:CuO ≤ 5) are studied. The conditions of the stable crystallization of Mn2+ 1−xCuxMoO4, Mn2 3+O3, Mn2+Mn2 3+O4, Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+- and Mn3+-containing Mn2+ 1−xCuxMoO4 and Mn2+Mn2 3+O4 and Mn2 3+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented.
AB - The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 ≤ Mn2O3:CuO ≤ 5) are studied. The conditions of the stable crystallization of Mn2+ 1−xCuxMoO4, Mn2 3+O3, Mn2+Mn2 3+O4, Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+- and Mn3+-containing Mn2+ 1−xCuxMoO4 and Mn2+Mn2 3+O4 and Mn2 3+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn2+ 1−xCuxMn3+BO4 and Mn2+ 2−xCuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented.
KW - A1.Characterization
KW - A2.Growth from solutions
KW - A2.Single crystal growth
KW - B1.Manganites
KW - B2.Magnetic materials
KW - Growth from solutions
KW - Single crystal growth
KW - Characterization
KW - MAGNETISM
KW - SINGLE-CRYSTALS
KW - GROWTH
KW - LUDWIGITE
KW - Magnetic materials
KW - Manganites
UR - http://www.scopus.com/inward/record.url?scp=85053797039&partnerID=8YFLogxK
U2 - 10.1016/j.jcrysgro.2018.09.011
DO - 10.1016/j.jcrysgro.2018.09.011
M3 - Article
AN - SCOPUS:85053797039
VL - 503
SP - 1
EP - 8
JO - Journal of Crystal Growth
JF - Journal of Crystal Growth
SN - 0022-0248
ER -
ID: 16703698