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Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid. / Demakov, P. A.; Sapchenko, S. A.; Samsonenko, D. G. et al.

In: Russian Chemical Bulletin, Vol. 67, No. 3, 01.03.2018, p. 490-496.

Research output: Contribution to journal › Article › peer-review

Harvard

Demakov, PA, Sapchenko, SA, Samsonenko, DG, Dybtsev, DN & Fedin, VP 2018, 'Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid', Russian Chemical Bulletin, vol. 67, no. 3, pp. 490-496. https://doi.org/10.1007/s11172-018-2098-3

APA

Demakov, P. A., Sapchenko, S. A., Samsonenko, D. G., Dybtsev, D. N., & Fedin, V. P. (2018). Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid. Russian Chemical Bulletin, 67(3), 490-496. https://doi.org/10.1007/s11172-018-2098-3

Vancouver

Demakov PA, Sapchenko SA, Samsonenko DG, Dybtsev DN, Fedin VP. Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid. Russian Chemical Bulletin. 2018 Mar 1;67(3):490-496. doi: 10.1007/s11172-018-2098-3

Author

Demakov, P. A. ; Sapchenko, S. A. ; Samsonenko, D. G. et al. / Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid. In: Russian Chemical Bulletin. 2018 ; Vol. 67, No. 3. pp. 490-496.

BibTeX

@article{015d99478fb848deaef36fcdf038fbeb,
title = "Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid",
abstract = "Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.",
keywords = "manganese, metal-organic coordination polymers, X-ray diffraction analysis, zinc, CARBOXYLATE, NANOPOROUS MATERIAL, METAL-ORGANIC FRAMEWORK",
author = "Demakov, {P. A.} and Sapchenko, {S. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",
year = "2018",
month = mar,
day = "1",
doi = "10.1007/s11172-018-2098-3",
language = "English",
volume = "67",
pages = "490--496",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid

AU - Demakov, P. A.

AU - Sapchenko, S. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.

AB - Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.

KW - manganese

KW - metal-organic coordination polymers

KW - X-ray diffraction analysis

KW - zinc

KW - CARBOXYLATE

KW - NANOPOROUS MATERIAL

KW - METAL-ORGANIC FRAMEWORK

UR - http://www.scopus.com/inward/record.url?scp=85049313646&partnerID=8YFLogxK

U2 - 10.1007/s11172-018-2098-3

DO - 10.1007/s11172-018-2098-3

M3 - Article

AN - SCOPUS:85049313646

VL - 67

SP - 490

EP - 496

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 3

ER -

ID: 14316562