Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid. / Demakov, P. A.; Sapchenko, S. A.; Samsonenko, D. G. и др.
в: Russian Chemical Bulletin, Том 67, № 3, 01.03.2018, стр. 490-496.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid
AU - Demakov, P. A.
AU - Sapchenko, S. A.
AU - Samsonenko, D. G.
AU - Dybtsev, D. N.
AU - Fedin, V. P.
PY - 2018/3/1
Y1 - 2018/3/1
N2 - Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.
AB - Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.
KW - manganese
KW - metal-organic coordination polymers
KW - X-ray diffraction analysis
KW - zinc
KW - CARBOXYLATE
KW - NANOPOROUS MATERIAL
KW - METAL-ORGANIC FRAMEWORK
UR - http://www.scopus.com/inward/record.url?scp=85049313646&partnerID=8YFLogxK
U2 - 10.1007/s11172-018-2098-3
DO - 10.1007/s11172-018-2098-3
M3 - Article
AN - SCOPUS:85049313646
VL - 67
SP - 490
EP - 496
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 3
ER -
ID: 14316562