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Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids. / Seitz, Andreas E.; Vogel, Ulf; Eberl, Miriam et al.

In: Chemistry - A European Journal, Vol. 23, No. 43, 01.08.2017, p. 10319-10327.

Research output: Contribution to journal › Article › peer-review

Harvard

Seitz, AE, Vogel, U, Eberl, M, Eckhardt, M, Balázs, G, Peresypkina, EV, Bodensteiner, M, Zabel, M & Scheer, M 2017, 'Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids', Chemistry - A European Journal, vol. 23, no. 43, pp. 10319-10327. https://doi.org/10.1002/chem.201701380

APA

Seitz, A. E., Vogel, U., Eberl, M., Eckhardt, M., Balázs, G., Peresypkina, E. V., Bodensteiner, M., Zabel, M., & Scheer, M. (2017). Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids. Chemistry - A European Journal, 23(43), 10319-10327. https://doi.org/10.1002/chem.201701380

Vancouver

Seitz AE, Vogel U, Eberl M, Eckhardt M, Balázs G, Peresypkina EV et al. Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids. Chemistry - A European Journal. 2017 Aug 1;23(43):10319-10327. doi: 10.1002/chem.201701380

Author

Seitz, Andreas E. ; Vogel, Ulf ; Eberl, Miriam et al. / Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids. In: Chemistry - A European Journal. 2017 ; Vol. 23, No. 43. pp. 10319-10327.

BibTeX

@article{71d888aeb9c8437e89af00c6e4808cb4,
title = "Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids",
abstract = "A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.",
keywords = "coordination chemistry, DFT calculations, Lewis acids, NMR spectroscopy, phosphorus, TETRAHEDRO-TETRAPHOSPHORUS, TRANSITION-METAL-COMPLEXES, MOLECULAR-STRUCTURE, LIGAND COMPLEXES, P-4 ACTIVATION, ELEMENTS, CYCLO-TRIPHOSPHORUS, DINITROGEN, CHEMISTRY, WHITE PHOSPHORUS",
author = "Seitz, {Andreas E.} and Ulf Vogel and Miriam Eberl and Maria Eckhardt and G{\'a}bor Bal{\'a}zs and Peresypkina, {Eugenia V.} and Michael Bodensteiner and Manfred Zabel and Manfred Scheer",
note = "{\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2017",
month = aug,
day = "1",
doi = "10.1002/chem.201701380",
language = "English",
volume = "23",
pages = "10319--10327",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "43",

}

RIS

TY - JOUR

T1 - Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids

AU - Seitz, Andreas E.

AU - Vogel, Ulf

AU - Eberl, Miriam

AU - Eckhardt, Maria

AU - Balázs, Gábor

AU - Peresypkina, Eugenia V.

AU - Bodensteiner, Michael

AU - Zabel, Manfred

AU - Scheer, Manfred

N1 - © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2017/8/1

Y1 - 2017/8/1

N2 - A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.

AB - A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.

KW - coordination chemistry

KW - DFT calculations

KW - Lewis acids

KW - NMR spectroscopy

KW - phosphorus

KW - TETRAHEDRO-TETRAPHOSPHORUS

KW - TRANSITION-METAL-COMPLEXES

KW - MOLECULAR-STRUCTURE

KW - LIGAND COMPLEXES

KW - P-4 ACTIVATION

KW - ELEMENTS

KW - CYCLO-TRIPHOSPHORUS

KW - DINITROGEN

KW - CHEMISTRY

KW - WHITE PHOSPHORUS

UR - http://www.scopus.com/inward/record.url?scp=85021202505&partnerID=8YFLogxK

U2 - 10.1002/chem.201701380

DO - 10.1002/chem.201701380

M3 - Article

C2 - 28493497

AN - SCOPUS:85021202505

VL - 23

SP - 10319

EP - 10327

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 43

ER -

ID: 10098848