Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids. / Seitz, Andreas E.; Vogel, Ulf; Eberl, Miriam и др.
в: Chemistry - A European Journal, Том 23, № 43, 01.08.2017, стр. 10319-10327.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids
AU - Seitz, Andreas E.
AU - Vogel, Ulf
AU - Eberl, Miriam
AU - Eckhardt, Maria
AU - Balázs, Gábor
AU - Peresypkina, Eugenia V.
AU - Bodensteiner, Michael
AU - Zabel, Manfred
AU - Scheer, Manfred
N1 - © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2017/8/1
Y1 - 2017/8/1
N2 - A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.
AB - A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.
KW - coordination chemistry
KW - DFT calculations
KW - Lewis acids
KW - NMR spectroscopy
KW - phosphorus
KW - TETRAHEDRO-TETRAPHOSPHORUS
KW - TRANSITION-METAL-COMPLEXES
KW - MOLECULAR-STRUCTURE
KW - LIGAND COMPLEXES
KW - P-4 ACTIVATION
KW - ELEMENTS
KW - CYCLO-TRIPHOSPHORUS
KW - DINITROGEN
KW - CHEMISTRY
KW - WHITE PHOSPHORUS
UR - http://www.scopus.com/inward/record.url?scp=85021202505&partnerID=8YFLogxK
U2 - 10.1002/chem.201701380
DO - 10.1002/chem.201701380
M3 - Article
C2 - 28493497
AN - SCOPUS:85021202505
VL - 23
SP - 10319
EP - 10327
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 43
ER -
ID: 10098848