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Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF. / Chupina, A. V.; Mukhacheva, A. A.; Abramov, P. A. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 2, 01.02.2020, p. 299-308.

Research output: Contribution to journal › Article › peer-review

Harvard

Chupina, AV, Mukhacheva, AA, Abramov, PA & Sokolov, MN 2020, 'Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF', Journal of Structural Chemistry, vol. 61, no. 2, pp. 299-308. https://doi.org/10.1134/S0022476620020158

APA

Chupina, A. V., Mukhacheva, A. A., Abramov, P. A., & Sokolov, M. N. (2020). Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF. Journal of Structural Chemistry, 61(2), 299-308. https://doi.org/10.1134/S0022476620020158

Vancouver

Chupina AV, Mukhacheva AA, Abramov PA, Sokolov MN. Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF. Journal of Structural Chemistry. 2020 Feb 1;61(2):299-308. doi: 10.1134/S0022476620020158

Author

Chupina, A. V. ; Mukhacheva, A. A. ; Abramov, P. A. et al. / Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 2. pp. 299-308.

BibTeX

@article{a499488dbedc40acbac87e0e8faa83da,
title = "Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF",
abstract = "In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.",
keywords = "crystal structure, octamolybdate, silver, OXIDATION, CLUSTERS, CRYSTAL-STRUCTURE, POLYOXOMETALATE, COORDINATION",
author = "Chupina, {A. V.} and Mukhacheva, {A. A.} and Abramov, {P. A.} and Sokolov, {M. N.}",
year = "2020",
month = feb,
day = "1",
doi = "10.1134/S0022476620020158",
language = "English",
volume = "61",
pages = "299--308",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF

AU - Chupina, A. V.

AU - Mukhacheva, A. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

AB - In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

KW - crystal structure

KW - octamolybdate

KW - silver

KW - OXIDATION

KW - CLUSTERS

KW - CRYSTAL-STRUCTURE

KW - POLYOXOMETALATE

KW - COORDINATION

UR - http://www.scopus.com/inward/record.url?scp=85088525488&partnerID=8YFLogxK

U2 - 10.1134/S0022476620020158

DO - 10.1134/S0022476620020158

M3 - Article

AN - SCOPUS:85088525488

VL - 61

SP - 299

EP - 308

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 24833285