Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF. / Chupina, A. V.; Mukhacheva, A. A.; Abramov, P. A. и др.
в: Journal of Structural Chemistry, Том 61, № 2, 01.02.2020, стр. 299-308.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF
AU - Chupina, A. V.
AU - Mukhacheva, A. A.
AU - Abramov, P. A.
AU - Sokolov, M. N.
PY - 2020/2/1
Y1 - 2020/2/1
N2 - In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.
AB - In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.
KW - crystal structure
KW - octamolybdate
KW - silver
KW - OXIDATION
KW - CLUSTERS
KW - CRYSTAL-STRUCTURE
KW - POLYOXOMETALATE
KW - COORDINATION
UR - http://www.scopus.com/inward/record.url?scp=85088525488&partnerID=8YFLogxK
U2 - 10.1134/S0022476620020158
DO - 10.1134/S0022476620020158
M3 - Article
AN - SCOPUS:85088525488
VL - 61
SP - 299
EP - 308
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 2
ER -
ID: 24833285