Research output: Contribution to journal › Article › peer-review
Chlorobismuthates Trapping Dibromine : Formation of Two-Dimensional Supramolecular Polyhalide Networks with Br2 Linkers. / Adonin, Sergey A.; Gorokh, Igor D.; Abramov, Pavel A. et al.
In: European Journal of Inorganic Chemistry, Vol. 2017, No. 42, 16.11.2017, p. 4925-4929.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Chlorobismuthates Trapping Dibromine
T2 - Formation of Two-Dimensional Supramolecular Polyhalide Networks with Br2 Linkers
AU - Adonin, Sergey A.
AU - Gorokh, Igor D.
AU - Abramov, Pavel A.
AU - Novikov, Alexander S.
AU - Korolkov, Ilya V.
AU - Sokolov, Maxim N.
AU - Fedin, Vladimir P.
N1 - Publisher Copyright: © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/11/16
Y1 - 2017/11/16
N2 - Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′-propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two-dimensional polyhalide supramolecular networks. The nature of non-covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol.
AB - Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′-propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two-dimensional polyhalide supramolecular networks. The nature of non-covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol.
KW - Density functional calculations
KW - Halogens
KW - Halometalates
KW - Polyhalides
KW - QTAIM
UR - http://www.scopus.com/inward/record.url?scp=85034095768&partnerID=8YFLogxK
U2 - 10.1002/ejic.201700908
DO - 10.1002/ejic.201700908
M3 - Article
AN - SCOPUS:85034095768
VL - 2017
SP - 4925
EP - 4929
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 42
ER -
ID: 8968547