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Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands. / Konokhova, A. Yu; Afonin, M. Yu; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 8, 01.08.2020, p. 1244-1252.

Research output: Contribution to journal › Article › peer-review

Harvard

Konokhova, AY, Afonin, MY, Sukhikh, TS & Konchenko, SN 2020, 'Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands', Journal of Structural Chemistry, vol. 61, no. 8, pp. 1244-1252. https://doi.org/10.1134/S0022476620080090

APA

Konokhova, A. Y., Afonin, M. Y., Sukhikh, T. S., & Konchenko, S. N. (2020). Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands. Journal of Structural Chemistry, 61(8), 1244-1252. https://doi.org/10.1134/S0022476620080090

Vancouver

Konokhova AY, Afonin MY, Sukhikh TS, Konchenko SN. Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands. Journal of Structural Chemistry. 2020 Aug 1;61(8):1244-1252. doi: 10.1134/S0022476620080090

Author

Konokhova, A. Yu ; Afonin, M. Yu ; Sukhikh, T. S. et al. / Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 8. pp. 1244-1252.

BibTeX

@article{35681ecdc64744648c20b3674be6b6fd,
title = "Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands",
abstract = "Reactions of (FOrmula presented.) and (FOrmula presented.) (Cp* = η5-C5Me5) with polychalcogenide complexes of vanadium [(VMeCp)2(μ-S)(μ,η1:1-S2)(μ,η2:2-S2)], [(VMeCp)2(μ-Se)(μ,η1:1-Se2)(μ,η2:2-Se2)] (MeCp = C5H4Me), and [{V(nacnac)}2(μ-Te)2] ((nacnac) = (HC(C(Me)NC6H3–i-Pr2)2)) are studied. Finally, three chalcogenide complexes of ytterbium and samarium are obtained (FOrmula presented.)·2C7H8 (1·2C7H8), (FOrmula presented.) 0.6·[(Yb$$\text{Cp}_2^*$$)(μ,η1:2-Se2)(FOrmula presented.)]0.4·2C7H8 (2·2C7H8), (FOrmula presented.)2× ×(μ-Te)]·C7H8 (3·C7H8)) and one polysulfide vanadium complex [(VMeCp)2(μ-S)2(μ,η1:1-S2)] (4). The structure of the complexes is determined by single crystal X-ray diffraction.",
keywords = "binuclear complexes, crystal structure, samarium, selenium, sulfur, tellurium, vanadium, ytterbium, ACTIVATION, CLUSTERS",
author = "Konokhova, {A. Yu} and Afonin, {M. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",
year = "2020",
month = aug,
day = "1",
doi = "10.1134/S0022476620080090",
language = "English",
volume = "61",
pages = "1244--1252",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "8",

}

RIS

TY - JOUR

T1 - Binuclear chalcogenide complex of samarium and ytterbium with pentamethylcyclopentadienyl ligands

AU - Konokhova, A. Yu

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Reactions of (FOrmula presented.) and (FOrmula presented.) (Cp* = η5-C5Me5) with polychalcogenide complexes of vanadium [(VMeCp)2(μ-S)(μ,η1:1-S2)(μ,η2:2-S2)], [(VMeCp)2(μ-Se)(μ,η1:1-Se2)(μ,η2:2-Se2)] (MeCp = C5H4Me), and [{V(nacnac)}2(μ-Te)2] ((nacnac) = (HC(C(Me)NC6H3–i-Pr2)2)) are studied. Finally, three chalcogenide complexes of ytterbium and samarium are obtained (FOrmula presented.)·2C7H8 (1·2C7H8), (FOrmula presented.) 0.6·[(Yb$$\text{Cp}_2^*$$)(μ,η1:2-Se2)(FOrmula presented.)]0.4·2C7H8 (2·2C7H8), (FOrmula presented.)2× ×(μ-Te)]·C7H8 (3·C7H8)) and one polysulfide vanadium complex [(VMeCp)2(μ-S)2(μ,η1:1-S2)] (4). The structure of the complexes is determined by single crystal X-ray diffraction.

AB - Reactions of (FOrmula presented.) and (FOrmula presented.) (Cp* = η5-C5Me5) with polychalcogenide complexes of vanadium [(VMeCp)2(μ-S)(μ,η1:1-S2)(μ,η2:2-S2)], [(VMeCp)2(μ-Se)(μ,η1:1-Se2)(μ,η2:2-Se2)] (MeCp = C5H4Me), and [{V(nacnac)}2(μ-Te)2] ((nacnac) = (HC(C(Me)NC6H3–i-Pr2)2)) are studied. Finally, three chalcogenide complexes of ytterbium and samarium are obtained (FOrmula presented.)·2C7H8 (1·2C7H8), (FOrmula presented.) 0.6·[(Yb$$\text{Cp}_2^*$$)(μ,η1:2-Se2)(FOrmula presented.)]0.4·2C7H8 (2·2C7H8), (FOrmula presented.)2× ×(μ-Te)]·C7H8 (3·C7H8)) and one polysulfide vanadium complex [(VMeCp)2(μ-S)2(μ,η1:1-S2)] (4). The structure of the complexes is determined by single crystal X-ray diffraction.

KW - binuclear complexes

KW - crystal structure

KW - samarium

KW - selenium

KW - sulfur

KW - tellurium

KW - vanadium

KW - ytterbium

KW - ACTIVATION

KW - CLUSTERS

UR - http://www.scopus.com/inward/record.url?scp=85091356119&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/31331945-12bc-3c28-ad39-6da9d7e9e6a5/

U2 - 10.1134/S0022476620080090

DO - 10.1134/S0022476620080090

M3 - Article

AN - SCOPUS:85091356119

VL - 61

SP - 1244

EP - 1252

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 8

ER -

ID: 25605904