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Bimetallic Pt0.5Co0.5/SiO2 Catalyst : Preparation, Structure, and Properties in Preferential Oxidation of Carbon Monoxide. / Potemkin, D. I.; Konishcheva, M. V.; Zadesenets, A. V. et al.

In: Kinetics and Catalysis, Vol. 59, No. 4, 01.07.2018, p. 514-520.

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Potemkin DI, Konishcheva MV, Zadesenets AV, Snytnikov PV, Filatov EY, Korenev SV et al. Bimetallic Pt0.5Co0.5/SiO2 Catalyst: Preparation, Structure, and Properties in Preferential Oxidation of Carbon Monoxide. Kinetics and Catalysis. 2018 Jul 1;59(4):514-520. doi: 10.1134/S0023158418040110

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@article{056db1014da043b29d7dd2721f5e3f95,
title = "Bimetallic Pt0.5Co0.5/SiO2 Catalyst: Preparation, Structure, and Properties in Preferential Oxidation of Carbon Monoxide",
abstract = "The Pt0.5Со0.5/SiO2 catalyst has been prepared by the decomposition of a [Pt(NH3)4][Co(C2O4)2(H2O)2]. 2H2O binary complex salt supported in the pores of SiO2 pellets. It has been shown by a complex of physical and chemical methods that Pt0.5Со0.5/SiO2 contains alloy nanoparticles with an average composition Pt0.5Co0.5. The catalytic properties of Pt0.5Со0.5/SiO2 are studied in the preferential oxidation of СО in the reaction mixtures with various compositions. It was found that Pt0.5Со0.5/SiO2 has a high selectivity and makes it possible to decrease the outlet concentration of CO to a level of <10 ppm, and the presence of СО2 and/or Н2О in the reaction mixture almost does not affect its catalytic properties. The structure of the catalyst is stable under the conditions of preferential CO oxidation.",
keywords = "bimetallic catalysts, binary complex salts, preferential CO oxidation, selective CO oxidation, SELECTIVE OXIDATION, PERFORMANCE, DECOMPOSITION, STREAM, H-2-RICH GASES, PT-CO CATALYSTS, HYDROGEN, VAPOR, PT3CO",
author = "Potemkin, {D. I.} and Konishcheva, {M. V.} and Zadesenets, {A. V.} and Snytnikov, {P. V.} and Filatov, {E. Yu} and Korenev, {S. V.} and Sobyanin, {V. A.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = jul,
day = "1",
doi = "10.1134/S0023158418040110",
language = "English",
volume = "59",
pages = "514--520",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Bimetallic Pt0.5Co0.5/SiO2 Catalyst

T2 - Preparation, Structure, and Properties in Preferential Oxidation of Carbon Monoxide

AU - Potemkin, D. I.

AU - Konishcheva, M. V.

AU - Zadesenets, A. V.

AU - Snytnikov, P. V.

AU - Filatov, E. Yu

AU - Korenev, S. V.

AU - Sobyanin, V. A.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - The Pt0.5Со0.5/SiO2 catalyst has been prepared by the decomposition of a [Pt(NH3)4][Co(C2O4)2(H2O)2]. 2H2O binary complex salt supported in the pores of SiO2 pellets. It has been shown by a complex of physical and chemical methods that Pt0.5Со0.5/SiO2 contains alloy nanoparticles with an average composition Pt0.5Co0.5. The catalytic properties of Pt0.5Со0.5/SiO2 are studied in the preferential oxidation of СО in the reaction mixtures with various compositions. It was found that Pt0.5Со0.5/SiO2 has a high selectivity and makes it possible to decrease the outlet concentration of CO to a level of <10 ppm, and the presence of СО2 and/or Н2О in the reaction mixture almost does not affect its catalytic properties. The structure of the catalyst is stable under the conditions of preferential CO oxidation.

AB - The Pt0.5Со0.5/SiO2 catalyst has been prepared by the decomposition of a [Pt(NH3)4][Co(C2O4)2(H2O)2]. 2H2O binary complex salt supported in the pores of SiO2 pellets. It has been shown by a complex of physical and chemical methods that Pt0.5Со0.5/SiO2 contains alloy nanoparticles with an average composition Pt0.5Co0.5. The catalytic properties of Pt0.5Со0.5/SiO2 are studied in the preferential oxidation of СО in the reaction mixtures with various compositions. It was found that Pt0.5Со0.5/SiO2 has a high selectivity and makes it possible to decrease the outlet concentration of CO to a level of <10 ppm, and the presence of СО2 and/or Н2О in the reaction mixture almost does not affect its catalytic properties. The structure of the catalyst is stable under the conditions of preferential CO oxidation.

KW - bimetallic catalysts

KW - binary complex salts

KW - preferential CO oxidation

KW - selective CO oxidation

KW - SELECTIVE OXIDATION

KW - PERFORMANCE

KW - DECOMPOSITION

KW - STREAM

KW - H-2-RICH GASES

KW - PT-CO CATALYSTS

KW - HYDROGEN

KW - VAPOR

KW - PT3CO

UR - http://www.scopus.com/inward/record.url?scp=85051199353&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b8a4fa2f-d4af-3eb8-b248-34edc0102e33/

U2 - 10.1134/S0023158418040110

DO - 10.1134/S0023158418040110

M3 - Article

AN - SCOPUS:85051199353

VL - 59

SP - 514

EP - 520

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 4

ER -

ID: 16081136