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Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens. / Artemkina, Sofya; Poltarak, Anastasiia; Poltarak, Pavel et al.

In: Inorganica Chimica Acta, Vol. 512, 119875, 01.11.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Artemkina, S, Poltarak, A, Poltarak, P, Grayfer, E, Samsonenko, D & Fedorov, V 2020, 'Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens', Inorganica Chimica Acta, vol. 512, 119875. https://doi.org/10.1016/j.ica.2020.119875

APA

Artemkina, S., Poltarak, A., Poltarak, P., Grayfer, E., Samsonenko, D., & Fedorov, V. (2020). Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens. Inorganica Chimica Acta, 512, [119875]. https://doi.org/10.1016/j.ica.2020.119875

Vancouver

Artemkina S, Poltarak A, Poltarak P, Grayfer E, Samsonenko D, Fedorov V. Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens. Inorganica Chimica Acta. 2020 Nov 1;512:119875. doi: 10.1016/j.ica.2020.119875

Author

Artemkina, Sofya ; Poltarak, Anastasiia ; Poltarak, Pavel et al. / Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens. In: Inorganica Chimica Acta. 2020 ; Vol. 512.

BibTeX

@article{d98a6b8760e04bdf8820136b7d1afbfe,
title = "Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens",
abstract = "Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).",
keywords = "Amorphous metal polysulfides, Crystal structure, Dithiocarbamate ligand, Molybdenum pentasulfide, Triangular cluster complex, Tungsten pentasulfide, CONVERSION, CRYSTAL-STRUCTURE, SULFUR-DIOXIDE, COMPLEXES, ZIRCONIUM TRISULFIDE, STRUCTURAL-CHARACTERIZATION, POSITIVE-ELECTRODE, X-RAY PHOTOELECTRON, CLUSTER, ELECTRONIC-STRUCTURE",
author = "Sofya Artemkina and Anastasiia Poltarak and Pavel Poltarak and Ekaterina Grayfer and Denis Samsonenko and Vladimir Fedorov",
note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = nov,
day = "1",
doi = "10.1016/j.ica.2020.119875",
language = "English",
volume = "512",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens

AU - Artemkina, Sofya

AU - Poltarak, Anastasiia

AU - Poltarak, Pavel

AU - Grayfer, Ekaterina

AU - Samsonenko, Denis

AU - Fedorov, Vladimir

N1 - Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/11/1

Y1 - 2020/11/1

N2 - Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).

AB - Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).

KW - Amorphous metal polysulfides

KW - Crystal structure

KW - Dithiocarbamate ligand

KW - Molybdenum pentasulfide

KW - Triangular cluster complex

KW - Tungsten pentasulfide

KW - CONVERSION

KW - CRYSTAL-STRUCTURE

KW - SULFUR-DIOXIDE

KW - COMPLEXES

KW - ZIRCONIUM TRISULFIDE

KW - STRUCTURAL-CHARACTERIZATION

KW - POSITIVE-ELECTRODE

KW - X-RAY PHOTOELECTRON

KW - CLUSTER

KW - ELECTRONIC-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85088378834&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2020.119875

DO - 10.1016/j.ica.2020.119875

M3 - Article

AN - SCOPUS:85088378834

VL - 512

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119875

ER -

ID: 24814590