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Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens. / Artemkina, Sofya; Poltarak, Anastasiia; Poltarak, Pavel и др.
в: Inorganica Chimica Acta, Том 512, 119875, 01.11.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens
AU - Artemkina, Sofya
AU - Poltarak, Anastasiia
AU - Poltarak, Pavel
AU - Grayfer, Ekaterina
AU - Samsonenko, Denis
AU - Fedorov, Vladimir
N1 - Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/11/1
Y1 - 2020/11/1
N2 - Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).
AB - Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).
KW - Amorphous metal polysulfides
KW - Crystal structure
KW - Dithiocarbamate ligand
KW - Molybdenum pentasulfide
KW - Triangular cluster complex
KW - Tungsten pentasulfide
KW - CONVERSION
KW - CRYSTAL-STRUCTURE
KW - SULFUR-DIOXIDE
KW - COMPLEXES
KW - ZIRCONIUM TRISULFIDE
KW - STRUCTURAL-CHARACTERIZATION
KW - POSITIVE-ELECTRODE
KW - X-RAY PHOTOELECTRON
KW - CLUSTER
KW - ELECTRONIC-STRUCTURE
UR - http://www.scopus.com/inward/record.url?scp=85088378834&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2020.119875
DO - 10.1016/j.ica.2020.119875
M3 - Article
AN - SCOPUS:85088378834
VL - 512
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
M1 - 119875
ER -
ID: 24814590