Research output: Contribution to journal › Article › peer-review
Activation Parameters of Self-Diffusion of Aromatic Chiral Molecules in External Magnetic Fields. / Kozlova, Svetlana G.; Kompankov, Nikolay B.; Zavakhina, Marina S.
In: Journal of Physical Chemistry B, Vol. 121, No. 27, 13.07.2017, p. 6655-6658.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Activation Parameters of Self-Diffusion of Aromatic Chiral Molecules in External Magnetic Fields
AU - Kozlova, Svetlana G.
AU - Kompankov, Nikolay B.
AU - Zavakhina, Marina S.
PY - 2017/7/13
Y1 - 2017/7/13
N2 - The mobility of aromatic chiral molecules 1-phenylethanol and 1-phenyl-1-propanol in liquids was studied by 1H NMR spectroscopy depending on the strength of the external magnetic field, temperature, and concentration ratio of enantiomers. The data obtained were analyzed using Arrhenius law. The activation parameters were found to depend on the applied field. This effect is caused by the induced magnetic moments in aromatic molecules. The use of strong magnetic fields seems to be promising for investigation of intermolecular interactions of chiral molecules.
AB - The mobility of aromatic chiral molecules 1-phenylethanol and 1-phenyl-1-propanol in liquids was studied by 1H NMR spectroscopy depending on the strength of the external magnetic field, temperature, and concentration ratio of enantiomers. The data obtained were analyzed using Arrhenius law. The activation parameters were found to depend on the applied field. This effect is caused by the induced magnetic moments in aromatic molecules. The use of strong magnetic fields seems to be promising for investigation of intermolecular interactions of chiral molecules.
KW - NMR-SPECTROSCOPY
KW - GLYCEROL
KW - MAGNETIZABILITIES
KW - COEFFICIENTS
KW - COMPLEXES
KW - MIXTURES
KW - MOBILITY
KW - BINARY
UR - http://www.scopus.com/inward/record.url?scp=85024909482&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcb.7b05847
DO - 10.1021/acs.jpcb.7b05847
M3 - Article
C2 - 28628324
AN - SCOPUS:85024909482
VL - 121
SP - 6655
EP - 6658
JO - Journal of Physical Chemistry B
JF - Journal of Physical Chemistry B
SN - 1520-6106
IS - 27
ER -
ID: 9977312