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A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. / Cadiau, Amandine; Kolobov, Nikita; Srinivasan, Sivaranjani et al.

In: Angewandte Chemie - International Edition, Vol. 59, No. 32, 03.08.2020, p. 13468-13472.

Research output: Contribution to journal › Article › peer-review

Harvard

Cadiau, A, Kolobov, N, Srinivasan, S, Goesten, MG, Haspel, H, Bavykina, AV, Tchalala, MR, Maity, P, Goryachev, A, Poryvaev, AS, Eddaoudi, M, Fedin, MV, Mohammed, OF & Gascon, J 2020, 'A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity', Angewandte Chemie - International Edition, vol. 59, no. 32, pp. 13468-13472. https://doi.org/10.1002/anie.202000158

APA

Cadiau, A., Kolobov, N., Srinivasan, S., Goesten, M. G., Haspel, H., Bavykina, A. V., Tchalala, M. R., Maity, P., Goryachev, A., Poryvaev, A. S., Eddaoudi, M., Fedin, M. V., Mohammed, O. F., & Gascon, J. (2020). A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. Angewandte Chemie - International Edition, 59(32), 13468-13472. https://doi.org/10.1002/anie.202000158

Vancouver

Cadiau A, Kolobov N, Srinivasan S, Goesten MG, Haspel H, Bavykina AV et al. A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. Angewandte Chemie - International Edition. 2020 Aug 3;59(32):13468-13472. doi: 10.1002/anie.202000158

Author

Cadiau, Amandine ; Kolobov, Nikita ; Srinivasan, Sivaranjani et al. / A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. In: Angewandte Chemie - International Edition. 2020 ; Vol. 59, No. 32. pp. 13468-13472.

BibTeX

@article{de8d6d38edc5459eb9f0f78aed6018f6,
title = "A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity",
abstract = "The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.",
keywords = "hydrogen evolution, metal–organic frameworks, photo-oxidation, photocatalysis, titanium, TOPOLOGY, MOF, HYDROGEN-PRODUCTION, CO2 ADSORPTION, LIGAND, EFFICIENT, metal-organic frameworks",
author = "Amandine Cadiau and Nikita Kolobov and Sivaranjani Srinivasan and Goesten, {Maarten G.} and Henrik Haspel and Bavykina, {Anastasiya V.} and Tchalala, {Mohamed R.} and Partha Maity and Andrey Goryachev and Poryvaev, {Artem S.} and Mohamed Eddaoudi and Fedin, {Matvey V.} and Mohammed, {Omar F.} and Jorge Gascon",
note = "We thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey V. Fedin thanks the RFBR (18-29-04013). Amandine Cadiau thanks PIA for funding with the grant ANR-18-MOPGA-0009 {"}APPAT{"} and the Occitanie Region. {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2020",
month = aug,
day = "3",
doi = "10.1002/anie.202000158",
language = "English",
volume = "59",
pages = "13468--13472",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "32",

}

RIS

TY - JOUR

T1 - A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity

AU - Cadiau, Amandine

AU - Kolobov, Nikita

AU - Srinivasan, Sivaranjani

AU - Goesten, Maarten G.

AU - Haspel, Henrik

AU - Bavykina, Anastasiya V.

AU - Tchalala, Mohamed R.

AU - Maity, Partha

AU - Goryachev, Andrey

AU - Poryvaev, Artem S.

AU - Eddaoudi, Mohamed

AU - Fedin, Matvey V.

AU - Mohammed, Omar F.

AU - Gascon, Jorge

N1 - We thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey V. Fedin thanks the RFBR (18-29-04013). Amandine Cadiau thanks PIA for funding with the grant ANR-18-MOPGA-0009 "APPAT" and the Occitanie Region. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2020/8/3

Y1 - 2020/8/3

N2 - The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.

AB - The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.

KW - hydrogen evolution

KW - metal–organic frameworks

KW - photo-oxidation

KW - photocatalysis

KW - titanium

KW - TOPOLOGY

KW - MOF

KW - HYDROGEN-PRODUCTION

KW - CO2 ADSORPTION

KW - LIGAND

KW - EFFICIENT

KW - metal-organic frameworks

UR - http://www.scopus.com/inward/record.url?scp=85085499672&partnerID=8YFLogxK

U2 - 10.1002/anie.202000158

DO - 10.1002/anie.202000158

M3 - Article

C2 - 32315516

AN - SCOPUS:85085499672

VL - 59

SP - 13468

EP - 13472

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 32

ER -

ID: 24390194