Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. / Cadiau, Amandine; Kolobov, Nikita; Srinivasan, Sivaranjani и др.
в: Angewandte Chemie - International Edition, Том 59, № 32, 03.08.2020, стр. 13468-13472.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity
AU - Cadiau, Amandine
AU - Kolobov, Nikita
AU - Srinivasan, Sivaranjani
AU - Goesten, Maarten G.
AU - Haspel, Henrik
AU - Bavykina, Anastasiya V.
AU - Tchalala, Mohamed R.
AU - Maity, Partha
AU - Goryachev, Andrey
AU - Poryvaev, Artem S.
AU - Eddaoudi, Mohamed
AU - Fedin, Matvey V.
AU - Mohammed, Omar F.
AU - Gascon, Jorge
N1 - We thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey V. Fedin thanks the RFBR (18-29-04013). Amandine Cadiau thanks PIA for funding with the grant ANR-18-MOPGA-0009 "APPAT" and the Occitanie Region. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2020/8/3
Y1 - 2020/8/3
N2 - The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
AB - The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
KW - hydrogen evolution
KW - metal–organic frameworks
KW - photo-oxidation
KW - photocatalysis
KW - titanium
KW - TOPOLOGY
KW - MOF
KW - HYDROGEN-PRODUCTION
KW - CO2 ADSORPTION
KW - LIGAND
KW - EFFICIENT
KW - metal-organic frameworks
UR - http://www.scopus.com/inward/record.url?scp=85085499672&partnerID=8YFLogxK
U2 - 10.1002/anie.202000158
DO - 10.1002/anie.202000158
M3 - Article
C2 - 32315516
AN - SCOPUS:85085499672
VL - 59
SP - 13468
EP - 13472
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 32
ER -
ID: 24390194