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A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes. / Evtushok, Darya V.; Melnikov, Anatoly R.; Vorotnikova, Natalya A. et al.

In: Dalton Transactions, Vol. 46, No. 35, 21.09.2017, p. 11738-11747.

Research output: Contribution to journal › Article › peer-review

Harvard

Evtushok, DV, Melnikov, AR, Vorotnikova, NA, Vorotnikov, YA, Ryadun, AA, Kuratieva, NV, Kozyr, KV, Obedinskaya, NR, Kretov, EI, Novozhilov, IN, Mironov, YV, Stass, DV, Efremova, OA & Shestopalov, MA 2017, 'A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes', Dalton Transactions, vol. 46, no. 35, pp. 11738-11747. https://doi.org/10.1039/c7dt01919j

APA

Evtushok, D. V., Melnikov, A. R., Vorotnikova, N. A., Vorotnikov, Y. A., Ryadun, A. A., Kuratieva, N. V., Kozyr, K. V., Obedinskaya, N. R., Kretov, E. I., Novozhilov, I. N., Mironov, Y. V., Stass, D. V., Efremova, O. A., & Shestopalov, M. A. (2017). A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes. Dalton Transactions, 46(35), 11738-11747. https://doi.org/10.1039/c7dt01919j

Vancouver

Evtushok DV, Melnikov AR, Vorotnikova NA, Vorotnikov YA, Ryadun AA, Kuratieva NV et al. A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes. Dalton Transactions. 2017 Sept 21;46(35):11738-11747. doi: 10.1039/c7dt01919j

Author

Evtushok, Darya V. ; Melnikov, Anatoly R. ; Vorotnikova, Natalya A. et al. / A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes. In: Dalton Transactions. 2017 ; Vol. 46, No. 35. pp. 11738-11747.

BibTeX

@article{e5e7a800438648bcb364f5f8dc019d2a,
title = "A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes",
abstract = "Octahedral metal cluster complexes have high potential for biomedical applications. In order to evaluate the benefits of these moieties for combined CT/X-ray luminescence computed tomography, this paper compares photoluminescence, radiodensity and X-ray induced luminescence properties of eight related octahedral molybdenum and tungsten cluster complexes [{M6I8}L6]n (where M is Mo or W and L is I-, NO3 -, OTs- or OH-/H2O). This article demonstrates that despite the fact that molybdenum cluster complexes are better photoluminescence emitters, tungsten cluster complexes, in particular (Bu4N)2[{W6I8}I6], demonstrate significantly higher X-ray induced luminescence due to a combination of relatively good photoluminescence properties and high X-ray attenuation. Additionally, photo-degradation of [{M6I8}(NO3)6]2- was evaluated.",
keywords = "ORGANIC-INORGANIC HYBRIDS, METAL-CLUSTERS, CONTRAST AGENTS, CELLULAR INTERNALIZATION, COMPUTED-TOMOGRAPHY, ENERGY-TRANSFER, IODIDE CLUSTER, IN-VIVO, RHENIUM, WATER",
author = "Evtushok, {Darya V.} and Melnikov, {Anatoly R.} and Vorotnikova, {Natalya A.} and Vorotnikov, {Yuri A.} and Ryadun, {Alexey A.} and Kuratieva, {Natalia V.} and Kozyr, {Konstantin V.} and Obedinskaya, {Natalia R.} and Kretov, {Evgeniy I.} and Novozhilov, {Igor N.} and Mironov, {Yuri V.} and Stass, {Dmitri V.} and Efremova, {Olga A.} and Shestopalov, {Michael A.}",
year = "2017",
month = sep,
day = "21",
doi = "10.1039/c7dt01919j",
language = "English",
volume = "46",
pages = "11738--11747",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "35",

}

RIS

TY - JOUR

T1 - A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes

AU - Evtushok, Darya V.

AU - Melnikov, Anatoly R.

AU - Vorotnikova, Natalya A.

AU - Vorotnikov, Yuri A.

AU - Ryadun, Alexey A.

AU - Kuratieva, Natalia V.

AU - Kozyr, Konstantin V.

AU - Obedinskaya, Natalia R.

AU - Kretov, Evgeniy I.

AU - Novozhilov, Igor N.

AU - Mironov, Yuri V.

AU - Stass, Dmitri V.

AU - Efremova, Olga A.

AU - Shestopalov, Michael A.

PY - 2017/9/21

Y1 - 2017/9/21

N2 - Octahedral metal cluster complexes have high potential for biomedical applications. In order to evaluate the benefits of these moieties for combined CT/X-ray luminescence computed tomography, this paper compares photoluminescence, radiodensity and X-ray induced luminescence properties of eight related octahedral molybdenum and tungsten cluster complexes [{M6I8}L6]n (where M is Mo or W and L is I-, NO3 -, OTs- or OH-/H2O). This article demonstrates that despite the fact that molybdenum cluster complexes are better photoluminescence emitters, tungsten cluster complexes, in particular (Bu4N)2[{W6I8}I6], demonstrate significantly higher X-ray induced luminescence due to a combination of relatively good photoluminescence properties and high X-ray attenuation. Additionally, photo-degradation of [{M6I8}(NO3)6]2- was evaluated.

AB - Octahedral metal cluster complexes have high potential for biomedical applications. In order to evaluate the benefits of these moieties for combined CT/X-ray luminescence computed tomography, this paper compares photoluminescence, radiodensity and X-ray induced luminescence properties of eight related octahedral molybdenum and tungsten cluster complexes [{M6I8}L6]n (where M is Mo or W and L is I-, NO3 -, OTs- or OH-/H2O). This article demonstrates that despite the fact that molybdenum cluster complexes are better photoluminescence emitters, tungsten cluster complexes, in particular (Bu4N)2[{W6I8}I6], demonstrate significantly higher X-ray induced luminescence due to a combination of relatively good photoluminescence properties and high X-ray attenuation. Additionally, photo-degradation of [{M6I8}(NO3)6]2- was evaluated.

KW - ORGANIC-INORGANIC HYBRIDS

KW - METAL-CLUSTERS

KW - CONTRAST AGENTS

KW - CELLULAR INTERNALIZATION

KW - COMPUTED-TOMOGRAPHY

KW - ENERGY-TRANSFER

KW - IODIDE CLUSTER

KW - IN-VIVO

KW - RHENIUM

KW - WATER

UR - http://www.scopus.com/inward/record.url?scp=85029301374&partnerID=8YFLogxK

U2 - 10.1039/c7dt01919j

DO - 10.1039/c7dt01919j

M3 - Article

AN - SCOPUS:85029301374

VL - 46

SP - 11738

EP - 11747

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 35

ER -

ID: 9912845