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23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-. / Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Novozhilov, Igor N. et al.

In: Inorganic Chemistry, Vol. 57, No. 2, 16.01.2018, p. 811-820.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorotnikova, NA, Vorotnikov, YA, Novozhilov, IN, Syrokvashin, MM, Nadolinny, VA, Kuratieva, NV, Benoit, DM, Mironov, YV, Walton, RI, Clarkson, GJ, Kitamura, N, Sutherland, AJ, Shestopalov, MA & Efremova, OA 2018, '23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-', Inorganic Chemistry, vol. 57, no. 2, pp. 811-820. https://doi.org/10.1021/acs.inorgchem.7b02760

APA

Vorotnikova, N. A., Vorotnikov, Y. A., Novozhilov, I. N., Syrokvashin, M. M., Nadolinny, V. A., Kuratieva, N. V., Benoit, D. M., Mironov, Y. V., Walton, R. I., Clarkson, G. J., Kitamura, N., Sutherland, A. J., Shestopalov, M. A., & Efremova, O. A. (2018). 23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-. Inorganic Chemistry, 57(2), 811-820. https://doi.org/10.1021/acs.inorgchem.7b02760

Vancouver

Vorotnikova NA, Vorotnikov YA, Novozhilov IN, Syrokvashin MM, Nadolinny VA, Kuratieva NV et al. 23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-. Inorganic Chemistry. 2018 Jan 16;57(2):811-820. doi: 10.1021/acs.inorgchem.7b02760

Author

Vorotnikova, Natalya A. ; Vorotnikov, Yuri A. ; Novozhilov, Igor N. et al. / 23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-. In: Inorganic Chemistry. 2018 ; Vol. 57, No. 2. pp. 811-820.

BibTeX

@article{21f9bf2e77d24477b196e9d0fd01ea43,
title = "23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-",
abstract = "Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e- cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.",
keywords = "CRYSTAL-STRUCTURE, HEXANUCLEAR MOLYBDENUM, ELECTRONIC-STRUCTURE, VIBRATIONAL-SPECTRA, SOLUTION CHEMISTRY, CHLORIDE CLUSTER, BASIS-SETS, BR, REDOX, CL",
author = "Vorotnikova, {Natalya A.} and Vorotnikov, {Yuri A.} and Novozhilov, {Igor N.} and Syrokvashin, {Mikhail M.} and Nadolinny, {Vladimir A.} and Kuratieva, {Natalia V.} and Benoit, {David M.} and Mironov, {Yuri V.} and Walton, {Richard I.} and Clarkson, {Guy J.} and Noboru Kitamura and Sutherland, {Andrew J.} and Shestopalov, {Michael A.} and Efremova, {Olga A.}",
year = "2018",
month = jan,
day = "16",
doi = "10.1021/acs.inorgchem.7b02760",
language = "English",
volume = "57",
pages = "811--820",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "2",

}

RIS

TY - JOUR

T1 - 23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-

AU - Vorotnikova, Natalya A.

AU - Vorotnikov, Yuri A.

AU - Novozhilov, Igor N.

AU - Syrokvashin, Mikhail M.

AU - Nadolinny, Vladimir A.

AU - Kuratieva, Natalia V.

AU - Benoit, David M.

AU - Mironov, Yuri V.

AU - Walton, Richard I.

AU - Clarkson, Guy J.

AU - Kitamura, Noboru

AU - Sutherland, Andrew J.

AU - Shestopalov, Michael A.

AU - Efremova, Olga A.

PY - 2018/1/16

Y1 - 2018/1/16

N2 - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e- cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.

AB - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e- cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.

KW - CRYSTAL-STRUCTURE

KW - HEXANUCLEAR MOLYBDENUM

KW - ELECTRONIC-STRUCTURE

KW - VIBRATIONAL-SPECTRA

KW - SOLUTION CHEMISTRY

KW - CHLORIDE CLUSTER

KW - BASIS-SETS

KW - BR

KW - REDOX

KW - CL

UR - http://www.scopus.com/inward/record.url?scp=85040562203&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b02760

DO - 10.1021/acs.inorgchem.7b02760

M3 - Article

C2 - 29271200

AN - SCOPUS:85040562203

VL - 57

SP - 811

EP - 820

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 2

ER -

ID: 9266046