Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-. / Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Novozhilov, Igor N. и др.
в: Inorganic Chemistry, Том 57, № 2, 16.01.2018, стр. 811-820.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - 23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]-
AU - Vorotnikova, Natalya A.
AU - Vorotnikov, Yuri A.
AU - Novozhilov, Igor N.
AU - Syrokvashin, Mikhail M.
AU - Nadolinny, Vladimir A.
AU - Kuratieva, Natalia V.
AU - Benoit, David M.
AU - Mironov, Yuri V.
AU - Walton, Richard I.
AU - Clarkson, Guy J.
AU - Kitamura, Noboru
AU - Sutherland, Andrew J.
AU - Shestopalov, Michael A.
AU - Efremova, Olga A.
PY - 2018/1/16
Y1 - 2018/1/16
N2 - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e- cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.
AB - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e- cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.
KW - CRYSTAL-STRUCTURE
KW - HEXANUCLEAR MOLYBDENUM
KW - ELECTRONIC-STRUCTURE
KW - VIBRATIONAL-SPECTRA
KW - SOLUTION CHEMISTRY
KW - CHLORIDE CLUSTER
KW - BASIS-SETS
KW - BR
KW - REDOX
KW - CL
UR - http://www.scopus.com/inward/record.url?scp=85040562203&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.7b02760
DO - 10.1021/acs.inorgchem.7b02760
M3 - Article
C2 - 29271200
AN - SCOPUS:85040562203
VL - 57
SP - 811
EP - 820
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 2
ER -
ID: 9266046