Research output: Contribution to journal › Article › peer-review
1D and 2D Polybromotellurates(IV) : Structural Studies and Thermal Stability. / Usoltsev, Andrey N.; Adonin, Sergey A.; Abramov, Pavel A. et al.
In: European Journal of Inorganic Chemistry, Vol. 2018, No. 27, 23.07.2018, p. 3264-3269.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - 1D and 2D Polybromotellurates(IV)
T2 - Structural Studies and Thermal Stability
AU - Usoltsev, Andrey N.
AU - Adonin, Sergey A.
AU - Abramov, Pavel A.
AU - Novikov, Alexander S.
AU - Shayapov, Vladimir R.
AU - Plyusnin, Pavel E.
AU - Korolkov, Ilya V.
AU - Sokolov, Maxim N.
AU - Fedin, Vladimir P.
PY - 2018/7/23
Y1 - 2018/7/23
N2 - Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).
AB - Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).
KW - Noncovalent interactions
KW - Polyhalides
KW - QTAIM
KW - Tellurium
UR - http://www.scopus.com/inward/record.url?scp=85050405537&partnerID=8YFLogxK
U2 - 10.1002/ejic.201800383
DO - 10.1002/ejic.201800383
M3 - Article
AN - SCOPUS:85050405537
VL - 2018
SP - 3264
EP - 3269
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 27
ER -
ID: 15918988