Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands. / Savchenkov, Anton V.; Pirozhkov, Pavel A.; Vologzhanina, Anna V. и др.
в: ChemistrySelect, Том 4, № 29, 07.08.2019, стр. 8416-8423.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands
AU - Savchenkov, Anton V.
AU - Pirozhkov, Pavel A.
AU - Vologzhanina, Anna V.
AU - Zubavichus, Yan V.
AU - Dorovatovskii, Pavel V.
AU - Pushkin, Denis V.
AU - Serezhkina, Larisa B.
N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2019/8/7
Y1 - 2019/8/7
N2 - Crystal structures of three new uranyl compounds were solved using single crystal X-ray diffraction and studied using FTIR spectroscopy. Although the syntheses conditions were very similar differing only in the alkaline earth metal (Mg, Ca or Sr), the resulting structures are different, containing, respectively, mono-, tri- and hexanuclear metal-containing building units. This fact proves the profound crystal-chemical role of secondary metal atoms on the formation of crystal structures. Parameters of alkaline earth metal cations in the three newly synthesized compounds as well as in the earlier reported Ba-containing analog are discussed in detail using Voronoi–Dirichlet polyhedra and the method of intersecting spheres. Differences in packing of building units in the four mentioned compounds, as well as inter- and intramolecular noncovalent interactions in their structures are reported. The results of analysis are consistent with the stereoatomic model of crystal structures.
AB - Crystal structures of three new uranyl compounds were solved using single crystal X-ray diffraction and studied using FTIR spectroscopy. Although the syntheses conditions were very similar differing only in the alkaline earth metal (Mg, Ca or Sr), the resulting structures are different, containing, respectively, mono-, tri- and hexanuclear metal-containing building units. This fact proves the profound crystal-chemical role of secondary metal atoms on the formation of crystal structures. Parameters of alkaline earth metal cations in the three newly synthesized compounds as well as in the earlier reported Ba-containing analog are discussed in detail using Voronoi–Dirichlet polyhedra and the method of intersecting spheres. Differences in packing of building units in the four mentioned compounds, as well as inter- and intramolecular noncovalent interactions in their structures are reported. The results of analysis are consistent with the stereoatomic model of crystal structures.
KW - crotonate
KW - noncovalent interactions
KW - structure elucidation
KW - substructure
KW - uranyl
KW - VISUALIZATION
KW - TOPOLOGY
KW - URANIUM
KW - STEREOCHEMISTRY
KW - NEUTRON-DIFFRACTION
KW - CRYSTAL-STRUCTURES
KW - NONCOVALENT INTERACTIONS
KW - RB
KW - CS
KW - ACETATE
UR - http://www.scopus.com/inward/record.url?scp=85070203281&partnerID=8YFLogxK
U2 - 10.1002/slct.201901732
DO - 10.1002/slct.201901732
M3 - Article
AN - SCOPUS:85070203281
VL - 4
SP - 8416
EP - 8423
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 29
ER -
ID: 25464311