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Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands. / Savchenkov, Anton V.; Pirozhkov, Pavel A.; Vologzhanina, Anna V. et al.

In: ChemistrySelect, Vol. 4, No. 29, 07.08.2019, p. 8416-8423.

Research output: Contribution to journal › Article › peer-review

Harvard

Savchenkov, AV, Pirozhkov, PA, Vologzhanina, AV, Zubavichus, YV, Dorovatovskii, PV, Pushkin, DV & Serezhkina, LB 2019, 'Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands', ChemistrySelect, vol. 4, no. 29, pp. 8416-8423. https://doi.org/10.1002/slct.201901732

APA

Savchenkov, A. V., Pirozhkov, P. A., Vologzhanina, A. V., Zubavichus, Y. V., Dorovatovskii, P. V., Pushkin, D. V., & Serezhkina, L. B. (2019). Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands. ChemistrySelect, 4(29), 8416-8423. https://doi.org/10.1002/slct.201901732

Vancouver

Savchenkov AV, Pirozhkov PA, Vologzhanina AV, Zubavichus YV, Dorovatovskii PV, Pushkin DV et al. Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands. ChemistrySelect. 2019 Aug 7;4(29):8416-8423. doi: 10.1002/slct.201901732

Author

Savchenkov, Anton V. ; Pirozhkov, Pavel A. ; Vologzhanina, Anna V. et al. / Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands. In: ChemistrySelect. 2019 ; Vol. 4, No. 29. pp. 8416-8423.

BibTeX

@article{1d244e6494d1412d9880e45a26daab24,
title = "Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands",
abstract = "Crystal structures of three new uranyl compounds were solved using single crystal X-ray diffraction and studied using FTIR spectroscopy. Although the syntheses conditions were very similar differing only in the alkaline earth metal (Mg, Ca or Sr), the resulting structures are different, containing, respectively, mono-, tri- and hexanuclear metal-containing building units. This fact proves the profound crystal-chemical role of secondary metal atoms on the formation of crystal structures. Parameters of alkaline earth metal cations in the three newly synthesized compounds as well as in the earlier reported Ba-containing analog are discussed in detail using Voronoi–Dirichlet polyhedra and the method of intersecting spheres. Differences in packing of building units in the four mentioned compounds, as well as inter- and intramolecular noncovalent interactions in their structures are reported. The results of analysis are consistent with the stereoatomic model of crystal structures.",
keywords = "crotonate, noncovalent interactions, structure elucidation, substructure, uranyl, VISUALIZATION, TOPOLOGY, URANIUM, STEREOCHEMISTRY, NEUTRON-DIFFRACTION, CRYSTAL-STRUCTURES, NONCOVALENT INTERACTIONS, RB, CS, ACETATE",
author = "Savchenkov, {Anton V.} and Pirozhkov, {Pavel A.} and Vologzhanina, {Anna V.} and Zubavichus, {Yan V.} and Dorovatovskii, {Pavel V.} and Pushkin, {Denis V.} and Serezhkina, {Larisa B.}",
note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2019",
month = aug,
day = "7",
doi = "10.1002/slct.201901732",
language = "English",
volume = "4",
pages = "8416--8423",
journal = "ChemistrySelect",
issn = "2365-6549",
publisher = "Wiley-Blackwell",
number = "29",

}

RIS

TY - JOUR

T1 - Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands

AU - Savchenkov, Anton V.

AU - Pirozhkov, Pavel A.

AU - Vologzhanina, Anna V.

AU - Zubavichus, Yan V.

AU - Dorovatovskii, Pavel V.

AU - Pushkin, Denis V.

AU - Serezhkina, Larisa B.

N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2019/8/7

Y1 - 2019/8/7

N2 - Crystal structures of three new uranyl compounds were solved using single crystal X-ray diffraction and studied using FTIR spectroscopy. Although the syntheses conditions were very similar differing only in the alkaline earth metal (Mg, Ca or Sr), the resulting structures are different, containing, respectively, mono-, tri- and hexanuclear metal-containing building units. This fact proves the profound crystal-chemical role of secondary metal atoms on the formation of crystal structures. Parameters of alkaline earth metal cations in the three newly synthesized compounds as well as in the earlier reported Ba-containing analog are discussed in detail using Voronoi–Dirichlet polyhedra and the method of intersecting spheres. Differences in packing of building units in the four mentioned compounds, as well as inter- and intramolecular noncovalent interactions in their structures are reported. The results of analysis are consistent with the stereoatomic model of crystal structures.

AB - Crystal structures of three new uranyl compounds were solved using single crystal X-ray diffraction and studied using FTIR spectroscopy. Although the syntheses conditions were very similar differing only in the alkaline earth metal (Mg, Ca or Sr), the resulting structures are different, containing, respectively, mono-, tri- and hexanuclear metal-containing building units. This fact proves the profound crystal-chemical role of secondary metal atoms on the formation of crystal structures. Parameters of alkaline earth metal cations in the three newly synthesized compounds as well as in the earlier reported Ba-containing analog are discussed in detail using Voronoi–Dirichlet polyhedra and the method of intersecting spheres. Differences in packing of building units in the four mentioned compounds, as well as inter- and intramolecular noncovalent interactions in their structures are reported. The results of analysis are consistent with the stereoatomic model of crystal structures.

KW - crotonate

KW - noncovalent interactions

KW - structure elucidation

KW - substructure

KW - uranyl

KW - VISUALIZATION

KW - TOPOLOGY

KW - URANIUM

KW - STEREOCHEMISTRY

KW - NEUTRON-DIFFRACTION

KW - CRYSTAL-STRUCTURES

KW - NONCOVALENT INTERACTIONS

KW - RB

KW - CS

KW - ACETATE

UR - http://www.scopus.com/inward/record.url?scp=85070203281&partnerID=8YFLogxK

U2 - 10.1002/slct.201901732

DO - 10.1002/slct.201901732

M3 - Article

AN - SCOPUS:85070203281

VL - 4

SP - 8416

EP - 8423

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 29

ER -

ID: 25464311